The Drosophila of single-molecule magnetism: [Mn12O12(O2CR)16(H2O)4]

被引：596

作者：

Bagai, Rashmi ^{[1
]}

Christou, George ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 04期

关键词：

JAHN-TELLER ISOMERISM; HIGH-SPIN MOLECULES; STRUCTURAL-CHARACTERIZATION; MAGNETIZATION RELAXATION; ELECTRON REDUCTION; MN-12; COMPLEXES; CARBOXYLATE; SYMMETRY; CLUSTER; ACETATE;

D O I：

10.1039/b811963e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single-molecule magnets (SMMs) are individual molecules that can function as nanoscale magnetic particles. The [Mn12O12(O2CR)(16)(H2O)(4)] (Mn-12; R = Me, Et, etc.) family of SMMs was the first one discovered; it is also the one whose study has provided the majority of current knowledge on this interesting magnetic phenomenon, prompting its description here as the Drosophila of the field. This tutorial review will survey the various chemical studies that have been carried out to date on this family. This will include a discussion of methods that have been developed for their structural and redox transformation, and the effect of the latter on the magnetic and SMM properties.

引用

页码：1011 / 1026

页数：16

共 62 条

[41] Site-specific ligation of anthracene-1,8-dicarboxylates to an Mn12 core:: a route to the controlled functionalisation of single-molecule magnets [J].