Photonic crystal structures as a basis for a three-dimensionally interpenetrating electrochemical-cell system

被引:94
作者
Ergang, Nicholas S.
Lytle, Justin C.
Lee, Kyu T.
Oh, Seung M.
Smyrl, William H.
Stein, Andreas [1 ]
机构
[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA
[2] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151744, South Korea
[3] Seoul Natl Univ, Res Ctr Energy Convers & Storage, Seoul 151744, South Korea
关键词
D O I
10.1002/adma.200600295
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel interpenetrating electrode structure is synthesized by sequential assembly of nanostructured components throughout the interconnected macropores of an inverse opal carbon monolith. Separation of electrodes by a thin polymer electrolyte film prevents hard shorts and permits intercalation and shuttling of Li ions between electrodes (see figure and inside cover).
引用
收藏
页码:1750 / +
页数:5
相关论文
共 30 条
[1]   Doped vanadium oxides as host materials for lithium intercalation [J].
Coustier, F ;
Hill, J ;
Owens, BB ;
Passerini, S ;
Smyrl, WH .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (04) :1355-1360
[2]   Nanocomposite hybrid molecular materials for application in solid-state electrochemical supercapacitors [J].
Cuentas-Gallegos, AK ;
Lira-Cantu, M ;
Casañ-Pastor, N ;
Gómez-Romero, P .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (07) :1125-1133
[3]   Preparation of three dimensionally ordered macroporous Li0.35La0.55TiO3 by colloidal crystal templating process [J].
Dokko, K ;
Akutagawa, N ;
Isshiki, Y ;
Hoshina, K ;
Kanamura, K .
SOLID STATE IONICS, 2005, 176 (31-34) :2345-2348
[4]   Effect of a macropore structure on cycling rates of LiCoO2 [J].
Ergang, NS ;
Lytle, JC ;
Yan, HW ;
Stein, A .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (10) :A1989-A1995
[5]   Three dimensionally ordered composite solid materials for all solid-state rechargeable lithium batteries [J].
Kanamura, K ;
Akutagawa, N ;
Dokko, K .
JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :86-89
[6]   AEROGELS AND XEROGELS OF V2O5 AS INTERCALATION HOSTS [J].
LE, DB ;
PASSERINI, S ;
TIPTON, AL ;
OWENS, BB ;
SMYRL, WH .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (06) :L102-L103
[7]   Synthesis and rate performance of monolithic macroporous carbon electrodes for lithium-ion secondary batteries [J].
Lee, KT ;
Lytle, JC ;
Ergang, NS ;
Oh, SM ;
Stein, A .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (04) :547-556
[8]   Three-dimensional battery architectures [J].
Long, JW ;
Dunn, B ;
Rolison, DR ;
White, HS .
CHEMICAL REVIEWS, 2004, 104 (10) :4463-4492
[9]   Structural and electrochemical properties of three-dimensionally ordered macroporous tin(IV) oxide films [J].
Lytle, JC ;
Yan, HW ;
Ergang, NS ;
Smyrl, WH ;
Stein, A .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (10) :1616-1622
[10]   PERMEANT MOLECULAR-SIEVING WITH ELECTROCHEMICALLY PREPARED 6-NM FILMS OF POLY(PHENYLENE OXIDE) [J].
MCCARLEY, RL ;
IRENE, EA ;
MURRAY, RW .
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (06) :2492-2498