Hydrothermal synthesis, characterization and photocatalytic properties of Zn2SnO4 nanocrystal

被引：76

作者：

Lou, Xiangdong ^{[1
]}

Jia, Xiaohua

Xu, Jiaqiang

Liu, Shuangzhi

Gao, Qiaohuan

机构：

[1] Zhengzhou Univ, Coll Mat & Chem Engn, Zhengzhou 450002, Peoples R China

[2] Henan Normal Univ, Coll Chem & Environm Sci, Henan Key Lab Environm Pollut Control, Xinxiang 453007, Henan, Peoples R China

来源：

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2006年 / 432卷 / 1-2期

关键词：

nanometer material; spinel-type structure; Zn2SnO4; hydrothermal method; WASTE-WATER; REACTIVE DYES; DEGRADATION; CATALYST; ZNO; KINETICS;

D O I：

10.1016/j.msea.2006.06.010

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Spinel zinc stannate (Zn2SnO4) samples were prepared one-step by a hydrothermal process at 200 degrees C for 24h. The crystal structure of the samples was characterized by X-ray diffraction (XRD). The specific surface areas of the nanocrystal powders were measured by Brunauer-Emmett-Teller (BET) method with a gas adsorption analyzer. The crystal morphology and particle size were analyzed using a transmission electron microscopy (TEM). The results show that the product is polycrystalline Zn2SnO4, and the average specific surface area of nanocrystal powder is about 62 m(2)/g, the particles have mono-dispersive cubic shape and the grain size is about 20 nm. Furthermore, the photocatalytic activity of the samples was appraised by means of the liquid phase photocatalytic degradation of various water-soluble dyes (K-NR, B-RN and B-GFF) under UV and visible light irradiation. The effects of catalyst loading and reacting time on the photocatalytic activity were also investigated. The results show that Zn2SnO4 can photocatalytically decompose dyes in water solution after 2 h irradiation and the degradation can reach about 100%. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：221 / 225

页数：5

共 20 条

[11] Photocatalytic oxidation using a new catalyst -: TiO2 microsphere -: for water and wastewater treatment [J].

Li, XZ ;

Liu, H .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2003, 37 (17) :3989-3994

[12] Kinetics of heterogeneous photocatalytic degradation of reactive dyes in an immobilized TiO2 photocatalytic reactor [J].

Mahmoodi, NM ;

Arami, M ;

Limaee, NY ;

Tabrizi, NS .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2006, 295 (01) :159-164

[13] TIME-RESOLVED MICROWAVE CONDUCTIVITY .1. TIO2 PHOTOREACTIVITY AND SIZE QUANTIZATION [J].

MARTIN, ST ;

HERRMANN, H ;

CHOI, WY ;

HOFFMANN, MR .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1994, 90 (21) :3315-3322

[14] Solar photocatalytic degradation of a reactive azo dye in TiO2-suspension [J].

Muruganandham, M ;

Swaminathan, M .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2004, 81 (04) :439-457

[15] Photocatalytic degradation of organic compounds over combustion-synthesized nano-TiO2 [J].

Nagaveni, K ;

Sivalingam, G ;

Hegde, MS ;

Madras, G .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2004, 38 (05) :1600-1604

[16]

NIU MN, 1992, ACTA SCI NAT U INTRA, V4, P185

[17] Preparation, characterization and photocatalytic properties REFeO3 (RE = Sm, Eu, Gd) [J].

Niu, XS ;

Li, HH ;

Liu, GG .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 232 (1-2) :89-93

[18] An oxygen index evaluation of flammability for zinc hydroxystannate and zinc stannate as synergistic flame retardants for acrylonitrile-butadiene-styrene copolymer [J].

Petsom, A ;

Roengsumran, S ;

Ariyaphattanakul, A ;

Sangvanich, P .

POLYMER DEGRADATION AND STABILITY, 2003, 80 (01) :17-22

[19] Kinetics of photocatalytic degradation of reactive dyes in a TiO2 slurry reactor [J].

Sauer, T ;

Neto, GC ;

José, HJ ;

Moreira, RFPM .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 149 (1-3) :147-154

[20] Selective CO gas detection of Zn2SnO4 gas sensor [J].

Yu, JH ;

Choi, GM .

JOURNAL OF ELECTROCERAMICS, 2002, 8 (03) :249-255

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