Trends in optical nonlinearity and thermal stability in electrooptic chromophores based upon the 3-(dicyanomethylene)-2,3-dihydrobenzothiopene-1, 1-dioxide acceptor

被引：53

作者：

Hu, ZY

Fort, A

Barzoukas, M

Jen, AKY

Barlow, S

Marder, SR ^{[1
]}

机构：

[1] CALTECH, Beckman Inst, Pasadena, CA 91125 USA

[2] CNRS, UM 046, Inst Phys & Chem Mat Strasbourg, F-67037 Strasbourg, France

[3] ROI Technol, Opt Mat Div, Monmouth Jct, NJ 08852 USA

[4] Georgia Inst Technol, Sch Chem & Biochem, Atlanta, GA 30332 USA

[5] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA

[6] CALTECH, Jet Prop Lab, Pasadena, CA 91109 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2004年 / 108卷 / 25期

关键词：

D O I：

10.1021/jp036728u

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of new thiophene-bridged chromophores based on the powerful heterocyclic acceptor 3-(dicyanomethylene)-2,3-dihydrobenzothiophene-1,1-dioxide has been synthesized; the dependence of the linear and second-order nonlinear optical properties and thermal stability of these species upon the donor group and the bridging group have been studied. In addition, the synthesis of a related new acceptor, not containing the fused benzene ring, is described and a chromophore based upon this acceptor is studied.

引用

收藏

页码：8626 / 8630

页数：5

相关论文

共 71 条

[21] Photostability of electro-optic polymers possessing chromophores with efficient amino donors and cyano-containing acceptors [J].

Galvan-Gonzalez, A ;

Stegeman, GI ;

Jen, AKY ;

Wu, X ;

Canva, M ;

Kowalczyk, AC ;

Zhang, XQ ;

Lackritz, HS ;

Marder, S ;

Thayumanavan, S ;

Levina, G .

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 2001, 18 (12) :1846-1853

[22] SYNTHESIS OF DIARYLTHIOBARBITURIC ACID CHROMOPHORES WITH ENHANCED 2ND-ORDER OPTICAL NONLINEARITIES AND THERMAL-STABILITY [J].

GILMOUR, S ;

MONTGOMERY, RA ;

MARDER, SR ;

CHENG, LT ;

JEN, AKY ;

CAI, YM ;

PERRY, JW ;

DALTON, LR .

CHEMISTRY OF MATERIALS, 1994, 6 (10) :1603-1604

[23] THE INFLUENCE OF CHAIN-LENGTH AND ELECTRON-ACCEPTOR RESIDUES IN 3-SUBSTITUTED 7-N,N-DIETHYLAMINOCOUMARIN DYES [J].

GRIFFITHS, J ;

MILLAR, V ;

BAHRA, GS .

DYES AND PIGMENTS, 1995, 28 (04) :327-339

[24] Synthesis of chromophores with extremely high electro-optic activities. 2. Isophorone- and combined isophorone-thiophene-based chromophores [J].

He, MQ ;

Leslie, TM ;

Sinicropi, JA ;

Garner, SM ;

Reed, LD .

CHEMISTRY OF MATERIALS, 2002, 14 (11) :4669-4675

[25] New nonlinear optical chromophores exhibiting good transparency and large nonlinearity: synthesis and characterization of chromophores with stilbene and ring-locked triene as a combined conjugation bridge [J].

Hua, JL ;

Luo, JD ;

Qin, JG ;

Shen, YC ;

Zhang, Y ;

Lu, ZH .

JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (04) :863-867

[26] One-pot palladium-catalyzed highly chemo-, regio-, and stereoselective synthesis of trans-stilbene derivatives.: A concise and convenient synthesis of resveratrol [J].

Jeffery, T ;

Ferber, B .

TETRAHEDRON LETTERS, 2003, 44 (01) :193-197

[27] Synthesis and characterization of highly efficient and thermally stable diphenylamino-substituted thiophene stilbene chromophores for nonlinear optical applications [J].

Jen, AKY ;

Cai, YM ;

Bedworth, PV ;

Marder, SR .

ADVANCED MATERIALS, 1997, 9 (02) :132-135

[28]

Jen AKY, 1999, ADV MATER, V11, P452, DOI 10.1002/(SICI)1521-4095(199904)11:6<452::AID-ADMA452>3.0.CO

[29]

2-Y

[30] OPTIMIZATION OF THERMAL-STABILITY AND 2ND-ORDER NONLINEAR-OPTICAL PROPERTIES OF THIOPHENE DERIVED CHROMOPHORES [J].

JEN, AKY ;

RAO, VP ;

DROST, KJ ;

WONG, KY ;

CAVA, MP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (18) :2057-2058

← 1 2 3 4 5 6 7 8 →