Comparative catalytic C-H vs. C-Si activation of arenes with Pd complexes directed by urea or amide groups

被引：80

作者：

Rauf, Waqar ^{[1
]}

Thompson, Amber L. ^{[1
]}

Brown, John M. ^{[1
]}

机构：

[1] Univ Oxford, Chem Res Lab, Oxford OX2 7BL, England

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 26期

关键词：

BASIC HYDROLYSIS; PART; BOND; MECHANISM; OLEFINS; HYDROGENATION; PHENYLUREAS; VINYLATION; ANILIDES; SILICON;

D O I：

10.1039/b905717j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Analysis of regiocontrol in Pd-catalysed C-H activation leads to observations of aryltrimethylsilyl activation and to superior results with urea-based substrates.

引用

页码：3874 / 3876

页数：3

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