Micelle formation from amphiphilic "cylindrical brush" - Coil block copolymers prepared by metallocene catalysis

被引：67

作者：

Neiser, MW

Muth, S

Kolb, U

Harris, JR

Okuda, J

Schmidt, M

机构：

[1] Univ Mainz, Inst Phys Chem, D-55128 Mainz, Germany

[2] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany

[3] Univ Mainz, Inst Zool, D-55099 Mainz, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 24期

关键词：

block copolymers; metallocene catalysts; micelles; rod-coil polymers;

D O I：

10.1002/anie.200353259

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Giant rod-coil amphiphilic block copolymers were prepared by metallocene-catalyzed polymerization. The hydrophilic coiled block consists of polymethacrylic acid and the rod component of a hydrophobic cylindrical brush polymer. The high solubility of the stiff block results in the micelles being formed with the stiff block forming the solubilizing corona.

引用

页码：3192 / 3195

页数：4

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[41]

2-I

[42] Self-assembled nanostructure of a novel coil-rod diblock copolymer in dilute solution [J].