Solid state confinement of ferrocene by calixarenes

被引：25

作者：

Hardie, MJ ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

来源：

SUPRAMOLECULAR CHEMISTRY | 2002年 / 14卷 / 01期

基金：

澳大利亚研究理事会;

关键词：

solid state confinement; ferrocene; calixarenes; supramolecular complexation;

D O I：

10.1080/10610270290006529

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Combinations of ferrocene with unsubstituted calix [n]arenes, n = 4 and 5, in toluene afford crystalline inclusion complexes (calix[4]arene)3(ferrocene) [hexagonal, a = 14.7797(4), c = 18.4400(4) Angstrom, P6(3)/m, rho = 1.389 g.cm(-1), Z = 2, R-1 = 0.0963 (on 1401 observed data [I > 2sigma(I)])] as a lattice-type inclusion complex, and (calix[5]arene)(toluene)(0.55)(ferrocene)(0.45) [monoclinic, a = 9.6908(8), b = 15.069(1), c = 22.957(1) Angstrom, beta = 90.155(5)degrees, P2(1)/m, rho = 1.318 g.cm(-1), Z = 4, R-1 = 0.1005 (on 3130 observed data [I > 2sigma(I)])], that shows endocavity complexation of ferrocene by the calixarene.

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页码：7 / 10

页数：4

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