Integrated system for recovery of CaCO3, NaCl and MgSO4.7H2O from nanofiltration retentate

被引：148

作者：

Drioli, E

Curcio, E

Criscuoli, A

Di Profio, G

机构：

[1] Univ Calabria, Dept Chem Engn & Mat, I-87030 Commenda Di Rende, CS, Italy

[2] Univ Calabria, Inst Membrane Technol, CNR, I-87030 Commenda Di Rende, CS, Italy

来源：

JOURNAL OF MEMBRANE SCIENCE | 2004年 / 239卷 / 01期

关键词：

integrated membrane systems; seawater desalination; membrane contactors; calcium carbonate precipitation; membrane crystallization;

D O I：

10.1016/j.memsci.2003.09.028

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

An integrated membrane system has been developed in order to recover dissolved salts that are present, at low concentration, in typical feed streams to desalination plants. The experimental work aimed to obtain CaCO3, NaCl and MgSO(4)(.)7H(2)O as solid products from nanofiltration retentate. Since gypsum scale causes reduction Of SO42- content in the solution and drastically limits the recovery of epsomite, Ca2+ ions have been almost quantitatively precipitated by reaction with NaHCO3/Na2CO3. Sodium (bi)carbonate solutions have been produced by reactive absorption Of CO2 into sodium hydroxide solutions carried out by membrane contactors technology. The flow sheet has been completed with a membrane crystallization stage that allows the generation of supersaturation for salts crystallization. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：27 / 38

页数：12

共 54 条

[31]

[32] Environmental impacts of seawater distillation and reverse osmosis processes [J].

Morton, AJ ;

Callister, IK ;

Wade, NM .

DESALINATION, 1997, 108 (1-3) :1-10

[33] THE INCORPORATION OF MG2+ AND SR2+ INTO CALCITE OVERGROWTHS - INFLUENCES OF GROWTH-RATE AND SOLUTION COMPOSITION [J].

MUCCI, A ;

MORSE, JW .

GEOCHIMICA ET COSMOCHIMICA ACTA, 1983, 47 (02) :217-233

[34] INFLUENCE OF TEMPERATURE ON THE COMPOSITION OF MAGNESIAN CALCITE OVERGROWTHS PRECIPITATED FROM SEAWATER [J].

MUCCI, A .

GEOCHIMICA ET COSMOCHIMICA ACTA, 1987, 51 (07) :1977-1984

[35]

NELSON KH, 1954, J MAR RES, V13, P166

[36] REMOVAL OF CO2 BY GAS-ABSORPTION ACROSS A POLYMERIC MEMBRANE [J].

NII, S ;

TAKEUCHI, H ;

TAKAHASHI, K .

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1992, 25 (01) :67-72

[37] Integrated system for complete usage of components in seawater - A proposal of inorganic chemical combinat on seawater [J].

Ohya, H ;

Suzuki, T ;

Nakao, S .

DESALINATION, 2001, 134 (1-3) :29-36

[38] DISTRIBUTION COEFFICIENT OF MG-2+ IONS BETWEEN CALCITE AND SOLUTION AT 10-50-DEGREES-C [J].

OOMORI, T ;

KANESHIMA, H ;

MAEZATO, Y ;

KITANO, Y .

MARINE CHEMISTRY, 1987, 20 (04) :327-336

[39] Precipitation of calcium and magnesium carbonates from homogeneous supersaturated solutions [J].

Pokrovsky, OS .

JOURNAL OF CRYSTAL GROWTH, 1998, 186 (1-2) :233-239

[40] MICROPOROUS HOLLOW FIBERS FOR GAS-ABSORPTION .1. MASS-TRANSFER IN THE LIQUID [J].

ZHANG, Q ;

CUSSLER, EL .

JOURNAL OF MEMBRANE SCIENCE, 1985, 23 (03) :321-332

← 1 2 3 4 5 6 →