Anisotropic movements of coordination polymers upon desolvation: Solid-state transformation of a linear 1D coordination polymer to a ladderlike structure

被引：163

作者：

Nagarathinam, Mangayarkarasi ^{[1
]}

Vittal, Jagadese J. ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 26期

关键词：

crystal engineering; ladder polymers; silver; solid-state reactions; stacking interactions;

D O I：

10.1002/anie.200600376

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Rungs of a ladder: A solvated linear 1D coordination polymer [Ag(μ-bpe) (H2O)]-(CF3CO 2)·CH3CN (bpe = 4,4′-bipyridyl-ethylene) with no parallel dispositions of the double bonds in the crystal structure undergoes photodimerization when desolvated. This finding is attributed to the lateral movements of adjacent linear strands on desolvation, which form a ladderlike structure (see picture; Ag light blue, C gray, N purple, O red). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4337 / 4341

页数：5

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