A hydroformylation route to diazabicycloalkanes and oxazabicycloalkanes containing medium and large rings

被引：7

作者：

Bergmann, DJ

Campi, EM

Jackson, WR ^{[1
]}

Patti, AF

机构：

[1] Monash Univ, Dept Chem, Clayton, Vic 3800, Australia

[2] Monash Univ, Sch Appl Sci, Clayton, Vic 3800, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1999年 / 52卷 / 12期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1071/CH99097

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Diazabicycloalkanes and oxazabicycloalkanes containing medium and large rings can be prepared by rhodium-catalysed reactions of N-alkenylpropane-1,3-diamines and 2-(alkenylamino)ethanols with H-2/CO in excellent yields without the need for high dilution. Selective ring opening of these compounds can lead to large heterocycles.

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页码：1131 / 1138

页数：8

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