Tripodal amido complexes: Molecular "claws" in main group and transition metal chemistry

被引：139

作者：

Gade, LH ^{[1
]}

机构：

[1] Univ Strasbourg, Inst Le Bel, Lab Chim Organomet & Catalyse, CNRS,UMR 7513, F-67000 Strasbourg, France

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2002年 / 35卷 / 07期

关键词：

D O I：

10.1021/ar010116f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chemistry of transition metal amides has received new impetus in recent years due to the systematic exploitation of the amido function [NR2](-) in ligand design. A class of 3-fold symmetrical tripodal amido ligands has proved to be a valuable tool in the stabilization of early transition metal and main group metal complexes and complex fragments. Moreover, promising strategies for their use as chemical reagents and homogeneous catalysts have been developed. An overwiew of the current state of this field is given and the potential for further development will be highlighted.

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页码：575 / 582

页数：8

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