Preparation and characterization of a vanadium(III) dinitrogen complex supported by a tripodal anionic amide ligand

被引：28

作者：

Desmangles, N ^{[1
]}

Jenkins, H ^{[1
]}

Ruppa, KB ^{[1
]}

Gambarotta, S ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON,CANADA

来源：

INORGANICA CHIMICA ACTA | 1996年 / 250卷 / 1-2期

关键词：

crystal structures; vanadium complexes; dinitrogen complexes; tripodal amide ligand complexes;

D O I：

10.1016/S0020-1693(96)05323-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of VCl3(THF)(3) with [(CH3)(3)Si]NPhLi led to the formation of the corresponding tetrahedral {[(CH3)(3)Si]NPh}V-3(THF) complex. Conversely, the reaction of CH3C[(CH2)N(i-Pr)Li](3) (TIAME) with VCl3(THF)(3) gave the new dinitrogen complex (TIAME)V-N-2-V(TIAME) whose structure was determined by X-ray analysis.

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页码：1 / 4

页数：4

相关论文

共 53 条

[1] DINITROGEN COMPLEXES OF TRANSITION-METALS [J].

ALLEN, AD ;

HARRIS, RO ;

LOESCHER, BR ;

STEVENS, JR ;

WHITELEY, RN .

CHEMICAL REVIEWS, 1973, 73 (01) :11-20

[2]

[Anonymous], J CHEM SOC CHEM COMM

[3] PREPARATION, CHARACTERIZATION, AND REACTIVITY OF THE BINUCLEAR VANADIUM(III) COMPOUND ([(ME3SI)2N]V[MU-CH2SIME2N(SIME3)])2 - C-H SIGMA-BOND METATHESIS PROMOTED BY AN AMIDO FUNCTION [J].

BERNO, P ;

MINHAS, R ;

HAO, SK ;

GAMBAROTTA, S .

ORGANOMETALLICS, 1994, 13 (04) :1052-1054

[4] INSERTION VERSUS ELIMINATION IN THE REACTION OF BU(T)NC WITH A AZASILAVANADACYCLOBUTANE RING SUPPORTED BY HEXAMETHYLSILAZANATE LIGAND [J].

BERNO, P ;

GAMBAROTTA, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (20) :2419-2421

[5] REACTION OF A VANADIUM(III) AMIDE WITH H-2 - ISOLATION AND CHARACTERIZATION OF A POLYNUCLEAR MIXED-VALENCE POLYHYDRIDO-NITRIDO COMPLEX [J].

BERNO, P ;

GAMBAROTTA, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07) :822-824

[6] DINITROGEN FIXATION VERSUS METAL-METAL BOND FORMATION IN THE CHEMISTRY OF VANADIUM(II) AMIDINATES [J].

BERNO, P ;

HAO, SK ;

MINHAS, R ;

GAMBAROTTA, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (16) :7417-7418

[7]

BERNO P, 1994, ORGANOMETALLICS, V13, P259

[8] SYNTHESIS AND CHARACTERIZATION OF A THERMALLY ROBUST TITANIUM DINITROGEN COMPLEX - THE CRYSTAL-STRUCTURE OF [([(ME3SI)2N]TICL(PYRIDINE)2)2(MU-ETA-ETA'-N2)] [J].

BEYDOUN, N ;

DUCHATEAU, R ;

GAMBAROTTA, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (03) :244-246

[9] OXIDATION OF [OS(NH3)5CO]2+ TO [(OS(NH3)4CO)2N2]4+ [J].

BUHR, JD ;

TAUBE, H .

INORGANIC CHEMISTRY, 1979, 18 (08) :2208-2212

[10] ELECTRON-DEFICIENT VANADIUM ALKYL COMPLEXES - SYNTHESIS AND MOLECULAR-STRUCTURE OF THE VANADIUM(III) DINITROGEN COMPLEX [(ME3CCH2)3V]2(MU-N2) [J].

BUIJINK, JKF ;

MEETSMA, A ;

TEUBEN, JH .

ORGANOMETALLICS, 1993, 12 (06) :2004-2005

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