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Initialisation in RAFT-mediated polymerisation of methy acrylate

被引：85
作者：
McLeary, JB
McKenzie, JM
Tonge, MP
Sanderson, RD
Klumperman, B
机构：
[1] Univ Stellenbosch, Dept Chem & Polymer Sci, Ctr Macromol & Mat, UNESCO, ZA-7602 Matieland, South Africa
[2] Univ Stellenbosch, Nucl Magnet Resonance Labs, ZA-7602 Matieland, South Africa
[3] Univ Sydney, Sch Chem F11, Key Ctr Polymer Colloids, Sydney, NSW 2006, Australia
[4] Eindhoven Univ Technol, Polymer Chem Lab, NL-5600 MB Eindhoven, Netherlands
来源：
CHEMICAL COMMUNICATIONS | 2004年 / 17期
关键词：
D O I：
10.1039/b404857a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Inhibition in Reversible Addition-Fragmentation chain Transfer (RAFT)-mediated polymerisations is currently a controversial issue; here we provide evidence that the slow "propagation" of the initiating and leaving group radicals during the early part (the period of consumption of the initial RAFT agent) of methyl acrylate RAFT-mediated polymerisation has characteristics similar to inhibition.
引用
收藏
页码：1950 / 1951
页数：2
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