Nanostructured carbon-crystalline titania composites from microphase separation of poly(ethylene oxide-b-acrylonitrile) and titania sols

被引:28
作者
Stefik, Morgan [2 ]
Lee, Jinwoo [1 ]
Wiesner, Ulrich [2 ]
机构
[1] Pohang Univ Sci & Technol, Dept Chem Engn, Pohang 790784, Kyungbuk, South Korea
[2] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14853 USA
关键词
MESOPOROUS CARBON; METAL-OXIDES; NEGATIVE-ELECTRODE; LITHIUM BATTERIES; BLOCK-COPOLYMERS; POLYACRYLONITRILE; NANOPARTICLES; TEMPLATES; NANOTUBES; ACRYLONITRILE;
D O I
10.1039/b818972b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple "one-pot'' method utilizing a graphitic carbon source containing poly(ethylene oxide-b-acrylonitrile) diblock copolymer as a structure directing agent was used to synthesize carbon-crystalline titania composites as well as crystalline mesoporous titania materials after oxidative carbon removal.
引用
收藏
页码:2532 / 2534
页数:3
相关论文
共 27 条
[1]   Novel Non-Hydrolytic Sol-Gel Route to Metal Oxides [J].
Acosta, S. ;
Corriu, R. ;
Leclercq, D. ;
Mutin, P. H. ;
Vioux, A. .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1994, 2 (1-3) :25-28
[2]  
Donnet J.B., 1990, CARBON FIBERS
[3]   Properties of containing Sn nanoparticles activated carbon fiber for a negative electrode in lithium batteries [J].
Egashira, M ;
Takatsuji, H ;
Okada, S ;
Yamaki, J .
JOURNAL OF POWER SOURCES, 2002, 107 (01) :56-60
[4]   Ordered, nanostructured tin-based oxides/carbon composite as the negative-electrode material for lithium-ion batteries [J].
Fan, J ;
Wang, T ;
Yu, CZ ;
Tu, B ;
Jiang, ZY ;
Zhao, DY .
ADVANCED MATERIALS, 2004, 16 (16) :1432-+
[5]   Attachment of magnetic nanoparticles on carbon nanotubes and their soluble derivatives [J].
Georgakilas, V ;
Tzitzios, V ;
Gournis, D ;
Petridis, D .
CHEMISTRY OF MATERIALS, 2005, 17 (07) :1613-1617
[6]   The use of tin-decorated mesoporous carbon as an anode material for rechargeable lithium batteries [J].
Grigoriants, I ;
Sominski, L ;
Li, HL ;
Ifargan, I ;
Aurbach, D ;
Gedanken, A .
CHEMICAL COMMUNICATIONS, 2005, (07) :921-923
[7]   Nanostructured carbon arrays from block copolymers of polyacrylonitrile [J].
Kowalewski, T ;
Tsarevsky, NV ;
Matyjaszewski, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (36) :10632-10633
[8]   Well-defined poly(ethylene oxide)-polyacrylonitrile diblock copolymers as templates for mesoporous silicas and precursors for mesoporous carbons [J].
Kruk, M ;
Dufour, B ;
Celer, EB ;
Kowalewski, T ;
Jaroniec, M ;
Matyjaszewski, K .
CHEMISTRY OF MATERIALS, 2006, 18 (06) :1417-1424
[9]   Synthesis of mesoporous carbons using ordered and disordered mesoporous silica templates and polyacrylonitrile as carbon precursor [J].
Kruk, M ;
Dufour, B ;
Celer, EB ;
Kowalewski, T ;
Jaroniec, M ;
Matyjaszewski, K .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (19) :9216-9225
[10]   Tunable polyacrylonitrile-based micellar aggregates as a potential tool for the fabrication of carbon nanofibers [J].
Lazzari, M. ;
Scalarone, D. ;
Hoppe, C. E. ;
Vazquez-Vazquez, C. ;
Lopez-Quintela, M. A. .
CHEMISTRY OF MATERIALS, 2007, 19 (24) :5818-5820