In situ doping and crosslinking of fullerenes to form efficient and robust electron-transporting layers for polymer solar cells

被引:48
作者
Cho, Namchul [1 ]
Li, Chang-Zhi [1 ]
Yip, Hin-Lap [1 ]
Jen, Alex K. -Y. [1 ,2 ]
机构
[1] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
[2] Univ Washington, Dept Chem, Seattle, WA 98195 USA
关键词
OPEN-CIRCUIT VOLTAGE; ORGANIC ELECTRONICS; INTERFACIAL LAYER; HIGHLY EFFICIENT; PERFORMANCE; DEVICES; ENHANCEMENT; SURFACTANT; FILMS;
D O I
10.1039/c3ee42509f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Efficient electron-transporting layers (ETLs) with a stable conductive fullerene doped into a thermally crosslinkable fullerene matrix have been developed for inverted polymer solar cells (PSCs). The improved electrical conductivity and solvent resistance of these ETLs have significantly enhanced the performance of PSCs.
引用
收藏
页码:638 / 643
页数:6
相关论文
共 36 条
[1]   Enhanced Performance in Polymer Solar Cells by Surface Energy Control [J].
Bulliard, Xavier ;
Ihn, Soo-Ghang ;
Yun, Sungyoung ;
Kim, Yungi ;
Choi, Dukhyun ;
Choi, Jae-Young ;
Kim, Min ;
Sim, Myungsun ;
Park, Jong-Hwan ;
Choi, Woong ;
Cho, Kilwon .
ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (24) :4381-4387
[2]   In-situ Crosslinking and n-Doping of Semiconducting Polymers and Their Application as Efficient Electron-Transporting Materials in Inverted Polymer Solar Cells [J].
Cho, Namchul ;
Yip, Hin-Lap ;
Davies, Joshua A. ;
Kazarinoff, Peter D. ;
Zeigler, David F. ;
Durban, Matthew M. ;
Segawa, Yukari ;
O'Malley, Kevin M. ;
Luscombe, Christine K. ;
Jen, Alex K. -Y. .
ADVANCED ENERGY MATERIALS, 2011, 1 (06) :1148-1153
[3]   n-Doping of thermally polymerizable fullerenes as an electron transporting layer for inverted polymer solar cells [J].
Cho, Namchul ;
Yip, Hin-Lap ;
Hau, Steven K. ;
Chen, Kung-Shih ;
Kim, Tae-Wook ;
Davies, Joshua A. ;
Zeigler, David F. ;
Jen, Alex K. -Y. .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (19) :6956-6961
[4]   Efficient organic solar cells based on a double p-i-n architecture using doped wide-gap transport layers -: art. no. 244102 [J].
Drechsel, J ;
Männig, B ;
Kozlowski, F ;
Pfeiffer, M ;
Leo, K ;
Hoppe, H .
APPLIED PHYSICS LETTERS, 2005, 86 (24) :1-3
[5]   Interfacial Segregation in Polymer/Fullerene Blend Films for Photovoltaic Devices [J].
Germack, David S. ;
Chan, Calvin K. ;
Kline, R. Joseph ;
Fischer, Daniel A. ;
Gundlach, David J. ;
Toney, Michael F. ;
Richter, Lee J. ;
DeLongchamp, Dean M. .
MACROMOLECULES, 2010, 43 (08) :3828-3836
[6]   Substrate-dependent interface composition and charge transport in films for organic photovoltaics [J].
Germack, David S. ;
Chan, Calvin K. ;
Hamadani, Behrang H. ;
Richter, Lee J. ;
Fischer, Daniel A. ;
Gundlach, David J. ;
DeLongchamp, Dean M. .
APPLIED PHYSICS LETTERS, 2009, 94 (23)
[7]   Simultaneous Enhancement of Open-Circuit Voltage, Short-Circuit Current Density, and Fill Factor in Polymer Solar Cells [J].
He, Zhicai ;
Zhong, Chengmei ;
Huang, Xun ;
Wong, Wai-Yeung ;
Wu, Hongbin ;
Chen, Liwei ;
Su, Shijian ;
Cao, Yong .
ADVANCED MATERIALS, 2011, 23 (40) :4636-+
[8]   Highly Efficient and Stable Inverted Polymer Solar Cells Integrated with a Cross-Linked Fullerene Material as an Interlayer [J].
Hsieh, Chao-Hsiang ;
Cheng, Yen-Ju ;
Li, Pei-Jung ;
Chen, Chiu-Hsiang ;
Dubosc, Martin ;
Liang, Ru-Meng ;
Hsu, Chain-Shu .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (13) :4887-4893
[9]   Electrostatically Self-Assembled Nonconjugated Polyelectrolytes as an Ideal Interfacial Layer for Inverted Polymer Solar Cells [J].
Kang, Hongkyu ;
Hong, Soonil ;
Lee, Jongjin ;
Lee, Kwanghee .
ADVANCED MATERIALS, 2012, 24 (22) :3005-3009
[10]   Enhancement of field-effect mobility due to surface-mediated molecular ordering in regioregular polythiophene thin film transistors [J].
Kim, DH ;
Park, YD ;
Jang, YS ;
Yang, HC ;
Kim, YH ;
Han, JI ;
Moon, DG ;
Park, SJ ;
Chang, TY ;
Chang, CW ;
Joo, MK ;
Ryu, CY ;
Cho, KW .
ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (01) :77-82