Synthesis and characterization of nickel(II) bis(alkylthio)salen complexes

被引：24

作者：

Bohle, DS ^{[1
]}

Zafar, A ^{[1
]}

Goodson, PA ^{[1
]}

Jaeger, DA ^{[1
]}

机构：

[1] Univ Wyoming, Dept Chem, Laramie, WY 82071 USA

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 04期

关键词：

D O I：

10.1021/ic990950p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

NiX2(2-RSC6H4CH=NCH2CH2N=CHC6H4SR-2) (NiX2L; L = 5) (1a, X = Br, R = C6H13; 1b, X = Cl, R = C12H25) and NiX2(2-C6H13SC6H4CH2NHCH2CH2NHCH2C6H4SC6H13-2) (NiX2L; L = 6) (2a, X = Br; 2b, X = Cl; 2c, X = OClO3) were prepared from ligands 5 and 6, respectively. The 1:2 metal-ligand complex Ni(OClO3)(2)(2-RSC6H4CH2NHCH2CH2NHCH2C6H4SR-2)(2) 3, was obtained from an EtOH solution of 2c. The characterization of paramagnetic 1-3 included single-crystal X-ray diffraction studies of 1a and 3. Complex 2c converted into 3 in the presence of excess ligand 6 in CHCl3.

引用

页码：712 / 718

页数：7

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