Encapsulation of two aromatics by a carcerand-like capsule of nanometre-scale dimensions

被引:134
作者
MacGillivray, LR [1 ]
Diamente, PR [1 ]
Reid, JL [1 ]
Ripmeester, JA [1 ]
机构
[1] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada
关键词
D O I
10.1039/a909339g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Co-crystallization of C-methylcalix[4]resorcinarene 1 with 4,4'-bipyridine 2 in the presence of nitrobenzene 3 yields a six-component carcerand-like capsule, 2(1).4(2), held together by 16 hydrogen bonds, in which two molecules of 3 are aligned within the interior of the complex in a head-to-head fashion.
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页码:359 / 360
页数:2
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