Heterophanes with 1,3,5-triazines as subunits and thiol/disulfide redox switch

被引：13

作者：

Graubaum, H ^{[1
]}

Tittelbach, F ^{[1
]}

Lutze, G ^{[1
]}

Gloe, K ^{[1
]}

Mackrodt, M ^{[1
]}

机构：

[1] TECH UNIV DRESDEN,INST ANORGAN CHEM,D-8027 DRESDEN,GERMANY

来源：

JOURNAL FUR PRAKTISCHE CHEMIE-CHEMIKER-ZEITUNG | 1997年 / 339卷 / 01期

关键词：

D O I：

10.1002/prac.19973390108

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The synthesis and characterization of 5 new coronands 2a-e, containing two 1,3,5-triazine-thiols as subunits and redox-switch are described. Cryptands 3a-e with disulfide bridges were obtained by oxidation. Reduction of cryptands 3a-e yields back the coronands 2a-e. The different complexation properties of the macrocycles 2a-d and 3a-d toward TI(I), Ag(I) and Hg(II) are also reported.

引用

页码：55 / 58

页数：4

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