Defect-induced ferromagnetism in co-doped ZnO

被引:218
作者
Khare, Neeraj
Kappers, Menno J.
Wei, Ming
Blamire, Mark G.
MacManus-Driscoll, Judith L.
机构
[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England
[2] Indian Inst Technol Delhi, Phys Dept, New Delhi 110016, India
关键词
D O I
10.1002/adma.200502200
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel soft-solution technique is used to grow epitaxial Zn0.98CO0.02O films on the c-plane (0001) of a single-crystal sapphire substrate. Annealing the films in precisely controlled atmospheres shows that the ferromagnetism is not linked to the carrier-concentration density. Undertaking cyclic annealing studies in the presence or absence of Zn vapor (see figure) shows that Zn interstitials but not oxygen vacancies are the critical defects for inducing ferromagnetism.
引用
收藏
页码:1449 / +
页数:5
相关论文
共 28 条
[1]   SURFACE EFFECTS ON LOW-ENERGY CATHODOLUMINESCENCE OF ZINC-OXIDE [J].
BYLANDER, EG .
JOURNAL OF APPLIED PHYSICS, 1978, 49 (03) :1188-1195
[2]   Donor impurity band exchange in dilute ferromagnetic oxides [J].
Coey, JMD ;
Venkatesan, M ;
Fitzgerald, CB .
NATURE MATERIALS, 2005, 4 (02) :173-179
[3]   Ferromagnetism in Fe-doped SnO2 thin films [J].
Coey, JMD ;
Douvalis, AP ;
Fitzgerald, CB ;
Venkatesan, M .
APPLIED PHYSICS LETTERS, 2004, 84 (08) :1332-1334
[4]   Zener model description of ferromagnetism in zinc-blende magnetic semiconductors [J].
Dietl, T ;
Ohno, H ;
Matsukura, F ;
Cibert, J ;
Ferrand, D .
SCIENCE, 2000, 287 (5455) :1019-1022
[5]   Bound magnetic polaron interactions in insulating doped diluted magnetic semiconductors [J].
Durst, AC ;
Bhatt, RN ;
Wolff, PA .
PHYSICAL REVIEW B, 2002, 65 (23) :2352051-23520510
[6]   Effects of growth conditions on the emission properties of ZnO films prepared on Si(100) by rf magnetron sputtering [J].
Jeong, SH ;
Kim, JK ;
Lee, BT .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2003, 36 (16) :2017-2020
[7]   High throughput fabrication of transition-metal-doped epitaxial ZnO thin films: A series of oxide-diluted magnetic semiconductors and their properties [J].
Jin, ZW ;
Fukumura, T ;
Kawasaki, M ;
Ando, K ;
Saito, H ;
Sekiguchi, T ;
Yoo, YZ ;
Murakami, M ;
Matsumoto, Y ;
Hasegawa, T ;
Koinuma, H .
APPLIED PHYSICS LETTERS, 2001, 78 (24) :3824-3826
[8]   Magnetism in cobalt-doped Cu2O thin films without and with Al, V, or Zn codopants [J].
Kale, SN ;
Ogale, SB ;
Shinde, SR ;
Sahasrabuddhe, M ;
Kulkarni, VN ;
Greene, RL ;
Venkatesan, T .
APPLIED PHYSICS LETTERS, 2003, 82 (13) :2100-2102
[9]  
KAMINSKI A, 2002, PHYS REV LETT, V88, P247
[10]  
Kittilstved K. R., 2005, PHYS REV LETT, V94, P147