X-ray crystal structure of the bis(dihydrogen) complex RuH2(H2)2(PCy3)2

被引：41

作者：

Borowski, AF

Donnadieu, B

Daran, JC

Sabo-Etienne, S

Chaudret, B

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France

[2] Polish Acad Sci, Inst Coal Chem, PL-44121 Gliwice, Poland

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 07期

关键词：

D O I：

10.1039/a908567j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

RuH2(H-2)(2)(PCy3)(2), the first reported stable bis (dihydrogen) complex crystallizes in the P1 space group; the two dihydrogen ligands lie in the equatorial plane in a mutual cis position and are located trans to the hydride ligands; the H-H distances are ca. 0.85 Angstrom, in agreement with the presence of unstretched dihydrogen ligands; these results are compared with previous theoretical calculations using density functional theory.

引用

页码：543 / 544

页数：2

共 34 条

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