DNA-templated synthesis in three dimensions: Introducing a micellar scaffold for organic reactions

被引：142

作者：

Alemdaroglu, Fikri E. ^{[1
]}

Ding, Ke ^{[1
]}

Berger, Ruediger ^{[1
]}

Herrmann, Andreas ^{[1
]}

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 25期

关键词：

biological organic hybrid materials; block copolymers; DNA; nanostructures; self-assembly;

D O I：

10.1002/anie.200600524

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Blocked up: Amphiphilic DNA-block copolymers were prepared in a fully automated single process by using a DNA synthesizer. These materials formed micelles in aqueous solution which were applied as a scaffold for DNA-templated organic reactions (see picture, red and green balls = reactants, yellow bar = new bond). For a novel fluorogenic reaction, the DNA-templated conversions were detected by fluorescence spectroscopy. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4206 / 4210

页数：5

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