Synthesis and X-ray crystal structure analysis of the first nickel bisoxazoline pincer complex

被引：44

作者：

Fossey, JS ^{[1
]}

Richards, CJ ^{[1
]}

机构：

[1] Univ London Queen Mary & Westfield Coll, Dept Chem, London E1 4NS, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 19期

关键词：

bisoxazoline; crystal structure; nickel; pincer complexes;

D O I：

10.1016/j.jorganchem.2004.06.055

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction in toluene between 2-iodo-1,3-bis(4',4'-dimethyl-2'-oxazolinyl)benzene and Ni(COD)(2) gave [2,6-bis(4',4'-dimethyl-2'-oxazolinyl)phenyl-N,C-1,N']iodonickle(II) isolated in 69% yield. The structure of this novel nickel bisoxazoline pincer complex was confirmed by a X-ray crystal structure analysis. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：3056 / 3059

页数：4

共 23 条

[1]

Albrecht M, 2001, ANGEW CHEM INT EDIT, V40, P3750, DOI 10.1002/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO

[2]

2-6

[3] Production of (R)-aminoglutethimide:: A new route from 1-chloro-4-nitrobenzene [J].

Bunegar, MJ ;

Dyer, UC ;

Evans, GR ;

Hewitt, RP ;

Jones, SW ;

Henderson, N ;

Richards, CJ ;

Sivaprasad, S ;

Skead, BM ;

Stark, MA ;

Teale, E .

ORGANIC PROCESS RESEARCH & DEVELOPMENT, 1999, 3 (06) :442-450

[4] Cyclopropanation with diazomethane and bis(oxazoline)palladium(II) complexes [J].

Denmark, SE ;

Stavenger, RA ;

Faucher, AM ;

Edwards, JP .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (10) :3375-3389

[5] Synthesis of 2,6-bis(2-oxazolinyl)phenylplatinum(II) NCN pincer complexes by direct cyclometalation. Catalysts for carbon-carbon bond formation [J].

Fossey, JS ;

Richards, CJ .

ORGANOMETALLICS, 2004, 23 (03) :367-373

[6] Catalysis of aldehyde and imine silylcyanation by platinum and palladium NCN-pincer complexes [J].

Fossey, JS ;

Richards, CJ .

TETRAHEDRON LETTERS, 2003, 44 (49) :8773-8776

[7] A direct route to platinum NCN-pincer complexes derived from 1,3-bis(imino)benzenes and an investigation into their activity as catalysts for carbon-carbon bond formation [J].

Fossey, JS ;

Richards, CJ .

ORGANOMETALLICS, 2002, 21 (24) :5259-5264

[8] Diaminoarylnickel(II) "pincer" complexes: Mechanistic considerations in the Kharasch addition reaction, controlled polymerization, and dendrimeric transition metal catalysts [J].

Gossage, RA ;

Van De Kuil, LA ;

Van Koten, G .

ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (07) :423-431

[9] ORGANONICKEL(II) COMPLEXES OF THE TERDENTATE MONOANIONIC LIGAND-OMICRON,OMICRON'-BIS[(DIMETHYLAMINO)METHYL]PHENYL (N-C-N) - SYNTHESES AND THE X-RAY CRYSTAL-STRUCTURE OF THE STABLE NICKEL(II) FORMATE [NI(N-C-N)O2CH] [J].

GROVE, DM ;

VANKOTEN, G ;

UBBELS, HJC ;

ZOET, R ;

SPEK, AL .

ORGANOMETALLICS, 1984, 3 (07) :1003-1009

[10] SYNTHESIS OF TRANS-15-NORMAL-BUTYL-16-METHYLDIHYDROPYRENE - SYNTHETIC ACCESS TO 1,2,3-TRISUBSTITUTED BENZENE-DERIVATIVES VIA DIRECT ALKYLATION OF 1,3-BIS(4',4'-DIMETHYL-2'-OXAZOLINYL)BENZENE [J].

HARRIS, TD ;

NEUSCHWANDER, B ;

BOEKELHEIDE, V .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (04) :727-730

← 1 2 3 →