Insights into the Heck reaction with PCP pincer palladium(II) complexes

被引：207

作者：

Eberhard, MR ^{[1
]}

机构：

[1] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1018 WV Amsterdam, Netherlands

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 13期

关键词：

D O I：

10.1021/ol049430a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Heck reaction of phenyl halides with styrene using a series of related PCP pincer palladium(III) complexes was studied in order to evaluate the effect of ligand structure and electronics on the catalytic activity and to investigate the nature of the catalyst species. We suggest these pincer complexes are precatalysts for highly active forms of metallic palladium. This conclusion is based on kinetic studies (induction periods, sigmoidal kinetics), Hg drop tests, quantitative poisoning experiments, and NMR studies.

引用

页码：2125 / 2128

页数：4

共 26 条

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