Effects of dissolved gas on emulsions, emulsion polymerization, and surfactant aggregation

被引：62

作者：

Karaman, ME ^{[1
]}

Ninham, BW ^{[1
]}

Pashley, RM ^{[1
]}

机构：

[1] AUSTRALIAN NATL UNIV, THE FACULTIES, DEPT CHEM, CANBERRA, ACT 0200, AUSTRALIA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 38期

关键词：

D O I：

10.1021/jp960758y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The presence of dissolved gas is shown to have a key role in emulsion stability and emulsion polymerization. The observations have implications for hydrophobic interactions, as well as chemical and biological reactivity. Hydrophobic and micellar surfaces may present favorable adsorption surfaces for dissolved gas as gas hydrates (i.e. clathrates) and/or submicrobubbles, and that concentrating the dissolved gas can lead ultimately to cavitation as the two such surfaces approach.

引用

页码：15503 / 15507

页数：5

共 55 条

[1]

ALFREDSSON B, 1961, SVENSSKA VETENSKADSK, V19

[2] STRUCTURAL-CHANGES IN THE SURFACE OF WATER [J].

BEAGLEHOLE, D .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (19) :5091-5092

[3] LARGE-SCALE CONDUCTANCE FLUCTUATIONS IN SOLUTIONS OF STRONG ELECTROLYTES [J].

BEZRUKOV, SM ;

PUSTOVOIT, MA ;

SIBILEV, AI ;

DRABKIN, GM .

PHYSICA B, 1989, 159 (03) :388-398

[4] STABILITY OF AQUEOUS FILMS ON HYDROPHOBIC METHYLATED SILICA [J].

BLAKE, TD ;

KITCHENE.JA .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1972, 68 (08) :1435-&

[5] THE SOLUBILITY OF GASES IN SOLUTIONS CONTAINING SODIUM ALKYLSULFATES OF VARIOUS CHAIN LENGTHS [J].

BOLDEN, PL ;

HOSKINS, JC ;

KING, AD .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1983, 91 (02) :454-463

[6]

BUNKIN NF, IN PRESS LANGMUIR

[7] FORCES BETWEEN FLUOROCARBON SURFACTANT MONOLAYERS - SALT EFFECTS ON THE HYDROPHOBIC INTERACTION [J].

CHRISTENSON, HK ;

CLAESSON, PM ;

BERG, J ;

HERDER, PC .

JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (04) :1472-1478

[8] CAVITATION AND THE INTERACTION BETWEEN MACROSCOPIC HYDROPHOBIC SURFACES [J].

CHRISTENSON, HK ;

CLAESSON, PM .

SCIENCE, 1988, 239 (4838) :390-392

[9] VERY LONG-RANGE ATTRACTIVE FORCES BETWEEN UNCHARGED HYDROCARBON AND FLUOROCARBON SURFACES IN WATER [J].

CLAESSON, PM ;

CHRISTENSON, HK .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (06) :1650-1655

[10] INTERACTIONS BETWEEN WATER-STABLE HYDROPHOBIC LANGMUIR-BLODGETT MONOLAYERS ON MICA [J].

CLAESSON, PM ;

BLOM, CE ;

HERDER, PC ;

NINHAM, BW .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1986, 114 (01) :234-242

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