Effects of dissolved gas on emulsions, emulsion polymerization, and surfactant aggregation

被引：62

作者：

Karaman, ME ^{[1
]}

Ninham, BW ^{[1
]}

Pashley, RM ^{[1
]}

机构：

[1] AUSTRALIAN NATL UNIV, THE FACULTIES, DEPT CHEM, CANBERRA, ACT 0200, AUSTRALIA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 38期

关键词：

D O I：

10.1021/jp960758y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The presence of dissolved gas is shown to have a key role in emulsion stability and emulsion polymerization. The observations have implications for hydrophobic interactions, as well as chemical and biological reactivity. Hydrophobic and micellar surfaces may present favorable adsorption surfaces for dissolved gas as gas hydrates (i.e. clathrates) and/or submicrobubbles, and that concentrating the dissolved gas can lead ultimately to cavitation as the two such surfaces approach.

引用

页码：15503 / 15507

页数：5

共 55 条

[11] EFFECT OF ELECTROLYTES ON BUBBLE COALESCENCE [J].

CRAIG, VSJ ;

NINHAM, BW ;

PASHLEY, RM .

NATURE, 1993, 364 (6435) :317-319

[12] THE EFFECT OF ELECTROLYTES ON BUBBLE COALESCENCE IN WATER [J].

CRAIG, VSJ ;

NINHAM, BW ;

PASHLEY, RM .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (39) :10192-10197

[13] PHYSICAL CHARACTERISTICS OF ULTRASTABLE LIPID-COATED MICROBUBBLES [J].

DARRIGO, JS ;

IMAE, T .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1992, 149 (02) :592-595

[14]

DARRIGO JS, 1986, STUDIES PHYSICAL THE, V40

[15] HYDROPHOBIC BOND IN MICELLAR SYSTEMS . EFFECTS OF VARIOUS ADDITIVES ON STABILITY OF MICELLES OF SODIUM DODECYL SULFATE AND OF N-DODECYLTRIMETHYLAMMONIUM BROMIDE [J].

EMERSON, MF ;

HOLTZER, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (10) :3320-&

[16] POLYHEDRAL CLATHRATE HYDRATES .2. STRUCTURE OF HYDRATE OF TETRA ISO-AMYL AMMONIUM FLUORIDE [J].

FEIL, D ;

JEFFREY, GA .

JOURNAL OF CHEMICAL PHYSICS, 1961, 35 (05) :1863-&

[17] WATER PERTURBATION CLOSE TO NONPOLAR GROUPS IN AQUEOUS-SOLUTIONS [J].

FINNEY, JL ;

SOPER, AK ;

TURNER, JZ .

PURE AND APPLIED CHEMISTRY, 1993, 65 (12) :2521-2526

[18] SOLVENT STRUCTURE AND PERTURBATIONS IN SOLUTIONS OF CHEMICAL AND BIOLOGICAL IMPORTANCE [J].

FINNEY, JL ;

SOPER, AK .

CHEMICAL SOCIETY REVIEWS, 1994, 23 (01) :1-10

[19]

FORSLIND E, 1975, WATER COMPREHENSIVE, V5, P223

[20] COVALENCY IN THE HYDROGEN BOND AND THE PROPERTIES OF WATER AND ICE [J].

FRANK, HS .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1958, 247 (1251) :481-492

← 1 2 3 4 5 6 →