Selective oxo functionalization of the uranyl ion with 3d metal cations

被引：128

作者：

Arnold, Polly L. ^{[1
]}

Patel, Dipti ^{[1
]}

Blake, Alexander J. ^{[1
]}

Wilson, Claire ^{[1
]}

Love, Jason B. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 30期

关键词：

D O I：

10.1021/ja0634167

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The linear uranyl dication [UO2]2+ can be bound in one of two coordination sites in the ditopic Pacman-shaped pyrrolic macrocyle H4L. Incorporation of Mn2+, Fe2+, or Co2+ cations in the second donor compartment affords the first uranyl complexes with a transition-metal-functionalized oxo group. Copyright © 2006 American Chemical Society.

引用

页码：9610 / 9611

页数：2

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