Purification and characterization of zeolite-supported single-walled carbon nanotubes catalytically synthesized from ethanol

被引：33

作者：

Igarashi, H

Murakami, H

Murakami, Y

Maruyama, S

Nakashima, N

机构：

[1] Nagasaki Univ, Grad Sch Sci & Technol, Dept Mat Sci, Bunkyo Ku, Nagasaki 8528521, Japan

[2] Univ Tokyo, Dept Mech Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2004年 / 392卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2004.05.104

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nearly complete removal of zeolite particles and Fe/Co catalysts from raw single-walled carbon nanotubes (SWNTs) produced by chemical vapor deposition was achieved by oxidation of raw material at 240degreesC or 340degreesC and treatment with 1% aqueous solution of hydrofluoric acid. The yields of SWNTs were estimated to be approximate to95% and the purities of SWNTs thus obtained were more than 95%, as characterized by thermo-gravimetric analysis. Raman spectra of the purified SWNTs were essentially identical with those of the corresponding raw samples. The raw and purified SWNTs were also characterized by EDX spectroscopy and transmission electron microscopy. (C) 2004 Elsevier B.V. All rights reserved.

引用

收藏

页码：529 / 532

页数：4

相关论文

共 13 条

[1] Characterization of single-walled carbon nanotubes (SWNTs) produced by CO disproportionation on Co-Mo catalysts [J].

Alvarez, WE ;

Pompeo, F ;

Herrera, JE ;

Balzano, L ;

Resasco, DE .

CHEMISTRY OF MATERIALS, 2002, 14 (04) :1853-1858

[2] Narrow (n,m)-distribution of single-walled carbon nanotubes grown using a solid supported catalyst [J].

Bachilo, SM ;

Balzano, L ;

Herrera, JE ;

Pompeo, F ;

Resasco, DE ;

Weisman, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (37) :11186-11187

[3] Structure-assigned optical spectra of single-walled carbon nanotubes [J].

Bachilo, SM ;

Strano, MS ;

Kittrell, C ;

Hauge, RH ;

Smalley, RE ;

Weisman, RB .

SCIENCE, 2002, 298 (5602) :2361-2366

[4] Gas-phase production of carbon single-walled nanotubes from carbon monoxide via the HiPco process: A parametric study [J].

Bronikowski, MJ ;

Willis, PA ;

Colbert, DT ;

Smith, KA ;

Smalley, RE .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2001, 19 (04) :1800-1805

[5] Purification and characterization of single-wall carbon nanotubes (SWNTs) obtained from the gas-phase decomposition of CO (HiPco process) [J].

Chiang, IW ;

Brinson, BE ;

Huang, AY ;

Willis, PA ;

Bronikowski, MJ ;

Margrave, JL ;

Smalley, RE ;

Hauge, RH .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (35) :8297-8301

[6]

Harris P.J.F., 1999, Carbon Nanotubes and Related Structures, DOI DOI 10.1017/CBO9780511605819

[7] HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].

IIJIMA, S .

NATURE, 1991, 354 (6348) :56-58

[8] Low-temperature synthesis of high-purity single-walled carbon nanotubes from alcohol [J].

Maruyama, S ;

Kojima, R ;

Miyauchi, Y ;

Chiashi, S ;

Kohno, M .

CHEMICAL PHYSICS LETTERS, 2002, 360 (3-4) :229-234

[9] Bulk production of quasi-aligned carbon nanotube bundles by the catalytic chemical vapour deposition (CCVD) method [J].

Mukhopadhyay, K ;

Koshio, A ;

Sugai, T ;

Tanaka, N ;

Shinohara, H ;

Konya, Z ;

Nagy, JB .

CHEMICAL PHYSICS LETTERS, 1999, 303 (1-2) :117-124

[10] Characterization of single-walled carbon nanotubes catalytically synthesized from alcohol [J].

Murakami, Y ;

Miyauchi, Y ;

Chiashi, S ;

Maruyama, S .

CHEMICAL PHYSICS LETTERS, 2003, 374 (1-2) :53-58