The crystal structure and hydrolysis equilibrium of triphenyl(2-mercapto-1-methylimidazolato)tin(IV)

被引：84

作者：

Casas, JS ^{[1
]}

Castineiras, A ^{[1
]}

Martinez, EG ^{[1
]}

Gonzalez, AS ^{[1
]}

Sanchez, A ^{[1
]}

Sordo, J ^{[1
]}

机构：

[1] UNIV SANTIAGO DE COMPOSTELA,DEPT QUIM INORGAN,E-15706 SANTIAGO COMPOSTE,GALICIA,SPAIN

来源：

POLYHEDRON | 1997年 / 16卷 / 05期

关键词：

tin; X-ray structure; NMR; triphenyltin complex;

D O I：

10.1016/S0277-5387(96)00341-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound was prepared from 1-methyl-2(3H)-imidazolinethione and triphenyltin(IV) hydroxide, and its crystal structure was determined by X-ray diffraction. The crystal consists of discrete molecules with the tin atom coordinated to one carbon atom of each of the three phenyl groups and to the sulfur atom of the deprotonated ligand. An Sn-N interaction [2.920(3) Angstrom] slightly distorts the tin coordination geometry from that of a perfect tetrahedron. NMR spectroscopy was used to study the hydrolysis of this compound in CDCl3. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：795 / 800

页数：6

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