共 27 条
Adsorption of 18-crown-6 from aqueous solution on granular activated carbon: A kinetic modeling study
被引:51
作者:
Azizian, Saeid
[1
]
Yahyaei, Bahare
[1
]
机构:
[1] Bu Ali Sina Univ, Fac Sci, Dept Chem, Hamadan, Iran
关键词:
adsorption;
kinetics;
18-crown-6;
pseudo-first-order;
pseudo-second-order;
granular activated carbon;
D O I:
10.1016/j.jcis.2006.01.058
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Granular activated carbon was used for the removal of 18-crown-6 from aqueous solution by adsorption. The influence of two experimental parameters, initial 18-crown-6 concentration and temperature, on the adsorption kinetics was evaluated. The kinetics data obtained were modeled by pseudo-first-order and pseudo-second-order models, respectively. The process of adsorption follows a pseudo-second-order rate model. The most important result of the present study is that the correlation coefficient is not a sufficient criterion for selection of a kinetic model, and therefore several criteria are suggested for its selection. (c) 2006 Elsevier Inc. All rights reserved.
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页码:112 / 115
页数:4
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