Iridium complex-catalyzed method for the construction of a quaternary carbon center α to allene

被引：30

作者：

Kezuka, S

Kanemoto, K

Takeuchi, R

机构：

[1] Aoyama Gakuin Univ, Dept Chem & Biol Sci, Sagamihara, Kanagawa 2298558, Japan

[2] Yokohama City Univ, Grad Sch Integrated Sci, Dept Chem, Kanazawa Ku, Yokohama, Kanagawa 2360027, Japan

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 34期

关键词：

quaternary carbon center; iridium; allylic alkylation; allene; nucleophilic substitution;

D O I：

10.1016/j.tetlet.2004.07.002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ir(cod)Cl](2)/dppe-catalyzed allylic alkylation of 1,1-disubstituted-2,3-butadienyl acetates gives a product bearing a quaternary carbon center alpha to allene in high yield, (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：6403 / 6406

页数：4