Application of olefin cross-metathesis to organometallics. Synthesis of unsaturated ferrocenyl alcohols and ketones

被引:22
作者
Seshadri, H [1 ]
Lovely, CJ [1 ]
机构
[1] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA
关键词
D O I
10.1021/ol991282e
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] The application of olefin cross metathesis to terminally unsaturated alpha-hydroxy- and alpha-ketoferrocenes is reported, Both substrates provided the terminally functionalized olefins in moderate to good yield. These examples represent the first cases of cross metathesis of substrates containing an organometallic functional group.
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页码:327 / 330
页数:4
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