Layer-by-layer surface modification and patterned electrostatic deposition of quantum dots

被引:120
作者
Jaffar, S
Nam, KT
Khademhosseini, A
Xing, J
Langer, RS
Belcher, AM [1 ]
机构
[1] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA
[2] MIT, Dept Chem Engn, Cambridge, MA 02139 USA
[3] MIT, Inst Soldier Nanotechnol, Cambridge, MA 02139 USA
[4] MIT, Div Biol Engn, Cambridge, MA 02139 USA
关键词
D O I
10.1021/nl0493287
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Modification of ZnS-capped CdSe quantum dot (QD) surfaces with polyelectrolyte coatings and subsequent layer-by-layer deposition to build hierarchical structures are presented. Mercaptoacetic acid (MAA)-treated QDs were sequentially coated with polyallylamine (PAA) and polyvinylsulfonic acid (PVSA) and analyzed using zeta potentials, absorbance spectra, and transmission electron microscopy. The modified QDs were deposited on patterned hyaluronic acid (HA) glass substrates to produce self-assembled heterostructures (QDs-MAA/QDs-PAA/HA/ glass), as revealed by fluorescence and atomic force microscopy.
引用
收藏
页码:1421 / 1425
页数:5
相关论文
共 31 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]   The use of nanocrystals in biological detection [J].
Alivisatos, P .
NATURE BIOTECHNOLOGY, 2004, 22 (01) :47-52
[3]   Growth of Si nanocrystals on alumina and integration in memory devices [J].
Baron, T ;
Fernandes, A ;
Damlencourt, JF ;
De Salvo, B ;
Martin, F ;
Mazen, F ;
Haukka, S .
APPLIED PHYSICS LETTERS, 2003, 82 (23) :4151-4153
[4]  
Caruso F, 2001, ADV MATER, V13, P11, DOI 10.1002/1521-4095(200101)13:1<11::AID-ADMA11>3.0.CO
[5]  
2-N
[6]   Quantum dot bioconjugates for ultrasensitive nonisotopic detection [J].
Chan, WCW ;
Nie, SM .
SCIENCE, 1998, 281 (5385) :2016-2018
[7]   Polyelectrolyte adsorption on charged particles: Ionic concentration and particle size effects - A Monte Carlo approach [J].
Chodanowski, P ;
Stoll, S .
JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (10) :4951-4960
[8]   Fluorescence resonance energy transfer between quantum dot donors and dye-labeled protein acceptors [J].
Clapp, AR ;
Medintz, IL ;
Mauro, JM ;
Fisher, BR ;
Bawendi, MG ;
Mattoussi, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (01) :301-310
[9]   Electroluminescence from single monolayers of nanocrystals in molecular organic devices [J].
Coe, S ;
Woo, WK ;
Bawendi, M ;
Bulovic, V .
NATURE, 2002, 420 (6917) :800-803
[10]   Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].
Decher, G .
SCIENCE, 1997, 277 (5330) :1232-1237