The first double oxidative addition of CH2Cl2 to a metal complex: facile synthesis of [Ru(CH2)Cl-2{P(C6H11)(3)}(2)]

被引：33

作者：

Olivan, M ^{[1
]}

Caulton, KG ^{[1
]}

机构：

[1] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 18期

关键词：

D O I：

10.1039/a703097e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Ru(H)(2)(H-2)(2)L-2] [L = P(C6H11)(3)] serves as a formal source of zerovalent 'RuL2', and undergoes unprecedented oxidative addition of both C-Cl bonds of CH2Cl2 to a single metal center, providing a convenient synthesis of the alkene metathesis catalyst [Ru(CH2)Cl2L2].

引用

页码：1733 / 1734

页数：2

共 16 条

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