REACTIONS OF CHLOROFORM AND GEM-DICHLOROCARBONS WITH BINUCLEAR RHODIUM COMPLEXES LEADING TO FUNCTIONALIZED METHYLENE-BRIDGED COMPOUNDS

被引:36
作者
CIRIANO, MA
TENA, MA
ORO, LA
机构
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 13期
关键词
D O I
10.1039/dt9920002123
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Chloroform and gem-dichlorocarbons CHCl2R (R = H, Ph or CO2Me) react rapidly with the binuclear basic metal complex [{Rh(mu-pz)(CNBut)2}2] (pz = pyrazolate) under a three-fragment four-electron scheme to give mainly the compounds [{Rh(mu-pz)Cl(CNBut)2}2(mu-CHR)] (R = Cl, H, CO2Me or Ph) and [{Rh(mu-pz)Cl(CNBut)2}2] as a side-product.
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页码:2123 / 2124
页数:2
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