Crystal structure of trans-tetrachlorobis[2-(2-1H-imidazolyl)-1H-imidazolium]cadmium(II),[Cd(H(3)biim)(2)Cl-4]

被引：8

作者：

Hester, C

Baughman, RG

Collier, H

机构：

[1] UNIV MISSOURI,DEPT CHEM,ROLLA,MO 65401

[2] NE MISSOURI STATE UNIV,DIV SCI,KIRKSVILLE,MO 63501

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1996年 / 26卷 / 10期

关键词：

crystal structure; 2,2'-bi-1H-imidazole; cadmium chloride;

D O I：

10.1007/BF01991966

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The reaction between cadmium(II) chloride and 2,2'-bi-1H-imidazole (H(2)biim) in an acidic solution affords [Cd(H(3)biim)(2)Cl-4] (H(3)biim=2-(2-1H-imidazolyl)-1H-imidazolium) in 63% yield. The compound crystallizes in the triclinic space group <P(1)over bar>, where a=8.072(2), b=8.100(2), c=8.593(2) Angstrom, alpha=75.89(2), beta=62.94(2), gamma=63.29(1)degrees, V=446.4(2) Angstrom(3), and Z=1. The central Cd atom exhibits an octahedral geometry composed of a Cl4N2 core. The Cd-N bond distance is 2.392(2) Angstrom. Cd-Cl distances are 2.5919(9) and 2.671(1) Angstrom.

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页码：695 / 699

页数：5

相关论文

共 28 条

[1] MULTIPLEX PROTON-TRANSFER AND ELECTRON-TRANSFER NATURES BASED ON THE 2,2'-BI-1H-IMIDAZOLE SYSTEM .1. ACID DISSOCIATION-CONSTANTS AND REDOX PROPERTIES IN SOLUTION [J].

AKUTAGAWA, T ;

SAITO, G .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1995, 68 (07) :1753-1773

[2] COPPER(II) COMPLEXES WITH 2,2'-BIIMIDAZOLE - PREPARATION AND CRYSTAL-STRUCTURE DETERMINATION OF A COMPLEX OF STOICHIOMETRY CU1.5CL3(H2BIM)2 (H2BIM=2,2'-BIIMIDAZOLE) [J].

BENCINI, A ;

MANI, F .

INORGANICA CHIMICA ACTA, 1988, 154 (02) :215-219

[3] Bis(1,1'-dimethyl-5-nitro-2,2'-biimidazol-3'-ium) trans-tetrachlorodimethylstannate [J].

Casas, JS ;

Castineiras, A ;

Martinez, G ;

Sordo, J ;

Varela, JM ;

Couce, MD .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 :2561-2563

[4] STRUCTURE OF 2,2'-BIIMIDAZOLE [J].

CROMER, DT ;

RYAN, RR ;

STORM, CB .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 :1435-1437

[5] THE CRYSTAL AND MOLECULAR-STRUCTURE OF CIS-DICHLOROBIS(2,2'-BIIMIDAZOLE)-IRON(III) CHLORIDE MONOHYDRATE [J].

DANCE, IG ;

ABUSHAMLEH, AS ;

GOODWIN, HA .

INORGANICA CHIMICA ACTA-ARTICLES, 1980, 43 (02) :217-221

[6]

Debus H., 1858, LIEBIGS ANN CHEM, V107, P199, DOI [10.1002/jlac.18581070209, DOI 10.1002/JLAC.18581070209]

[7] SYNTHESIS, ELECTRON-PARAMAGNETIC RESONANCE, AND MAGNETIC STUDIES OF BINUCLEAR BIS(ETA-5-CYCLOPENTADIENYL)TITANIUM(III) COMPOUNDS WITH BRIDGING PYRAZOLATE, BIIMIDAZOLATE, AND BIBENZIMIDAZOLATE ANIONS [J].

FIESELMANN, BF ;

HENDRICKSON, DN ;

STUCKY, GD .

INORGANIC CHEMISTRY, 1978, 17 (08) :2078-2084

[8] EVIDENCE FOR ENHANCEMENT OF CATALYSIS BY A 2ND METAL IN HETEROBINUCLEAR COMPLEXES - X-RAY STRUCTURE OF [H(CO)(PPH3)2RU(2,2'-BI-IMIDAZOLATO)RH(CYCLO-OCTA-1,5-DIENE)] [J].

GARCIA, MP ;

LOPEZ, AM ;

ESTERUELAS, MA ;

LAHOZ, FJ ;

ORO, LA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (12) :793-795

[9] DIORGANOTIN DIHALIDE COMPLEXES OF 2,2'-BIIMIDAZOLE - A PRELIMINARY-STUDY OF THEIR INHIBITORY EFFECTS ON CELL-DIVISION [J].

GONZALEZ, AS ;

CASAS, JS ;

SORDO, J ;

RUSSO, U ;

LAREO, MI ;

REGUEIRO, BJ .

JOURNAL OF INORGANIC BIOCHEMISTRY, 1990, 39 (03) :227-235

[10] MAGNETIC-EXCHANGE INTERACTIONS IN BINUCLEAR TRANSITION-METAL COMPLEXES .19. IMIDAZOLATE-BRIDGED AND BIIMIDAZOLATE-BRIDGED COPPER(II) COMPLEXES - CRYSTAL-STRUCTURE OF MU-BIIMIDAZOLATO-BIS(1,1,4,7,7-PENTAMETHYLDIETHYLENETRIAMINE)DICOPPER(II) TETRAPHENYLBORATE [J].

HADDAD, MS ;

DUESLER, EN ;

HENDRICKSON, DN .

INORGANIC CHEMISTRY, 1979, 18 (01) :141-148