Crystal structure of trans-tetrachlorobis[2-(2-1H-imidazolyl)-1H-imidazolium]cadmium(II),[Cd(H(3)biim)(2)Cl-4]

被引：8

作者：

Hester, C

Baughman, RG

Collier, H

机构：

[1] UNIV MISSOURI,DEPT CHEM,ROLLA,MO 65401

[2] NE MISSOURI STATE UNIV,DIV SCI,KIRKSVILLE,MO 63501

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1996年 / 26卷 / 10期

关键词：

crystal structure; 2,2'-bi-1H-imidazole; cadmium chloride;

D O I：

10.1007/BF01991966

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The reaction between cadmium(II) chloride and 2,2'-bi-1H-imidazole (H(2)biim) in an acidic solution affords [Cd(H(3)biim)(2)Cl-4] (H(3)biim=2-(2-1H-imidazolyl)-1H-imidazolium) in 63% yield. The compound crystallizes in the triclinic space group <P(1)over bar>, where a=8.072(2), b=8.100(2), c=8.593(2) Angstrom, alpha=75.89(2), beta=62.94(2), gamma=63.29(1)degrees, V=446.4(2) Angstrom(3), and Z=1. The central Cd atom exhibits an octahedral geometry composed of a Cl4N2 core. The Cd-N bond distance is 2.392(2) Angstrom. Cd-Cl distances are 2.5919(9) and 2.671(1) Angstrom.

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页码：695 / 699

页数：5

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