Resorcinarene-encapsulated nanoparticles: Building blocks for self-assembled nanostructures

被引：33

作者：

Wei, A ^{[1
]}

Kim, B ^{[1
]}

Pusztay, SV ^{[1
]}

Tripp, SL ^{[1
]}

Balasubramanian, R ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2001年 / 41卷 / 1-4期

关键词：

calixarenes; nanoparticles; self-assembly; sensors;

D O I：

10.1023/A:1014472212238

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Calix[4]resorcinarene-derived surfactants are highly effective at stabilizing metal nanoparticles of different sizes, creating opportunities to fabricate well-defined nanostructures with size-tunable materials properties. The resorcinarenes have a critical role in the dispersion of nanoparticles under various solvent conditions and in the robustness of the protective surfactant layer. Magnetic cobalt particles stabilized by resorcinarenes self-assemble into nanostructured "bracelets" in toluene. Resorcinarene surfactants can also promote the self-organization of gold nanoparticles as large as 170 nm into two-dimensional arrays. These nanostructured films possess novel optoelectronic properties such as surface-enhanced Raman scattering (SERS), and are expected to have useful applications for chemical sensing.

引用

页码：83 / 86

页数：4

共 26 条

[1] Self-assembly of a two-dimensional superlattice of molecularly linked metal clusters [J].