Zeolites as efficient catalysts for key transformations in carbohydrate chemistry

被引：36

作者：

Xavier, Nuno M. ^{[1
]}

Lucas, Susana D. ^{[1
]}

Rauter, Amelia P. ^{[1
]}

机构：

[1] Univ Lisbon, Dept Quim & Bioquim, Ctr Quim & Bioquim, Fac Ciencias, P-1749016 Lisbon, Portugal

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2009年 / 305卷 / 1-2期

关键词：

Acid zeolites; Heterogeneous catalysis; Carbohydrates; PER-O-ACETYLATION; ALKYL GLUCOSIDE SURFACTANTS; RUFF OXIDATIVE-DEGRADATION; FREE THERMAL DEHYDRATION; BETA-D-GLUCOPYRANOSIDES; ALPHA-PINENE OXIDE; ISOPROPYLIDENE DERIVATIVES; 1,2-TRANS GLYCOPYRANOSIDES; STEREOSELECTIVE-SYNTHESIS; RECENT PROGRESS;

D O I：

10.1016/j.molcata.2009.01.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Acid zeolites as catalysts offer unique achievements in the carbohydrate field allowing regio- and stereocontrolled reactions, mainly related to their shape-selective properties. Moreover, these materials are environmentally safe and easy to handle, contributing to clean and sustainable procedures in carbohydrate transformations. The scope of this review is to summarize the most significant applications of these heterogeneous catalysts in carbohydrate chemistry, notably in mediating key transformations such as glycosylation, sugar protection and deprotection, hydrolysis and dehydration, highlighting the exciting results that the use of zeolites may provide. (c) 2009 Elsevier B.V. All rights reserved.

引用

页码：84 / 89

页数：6

共 99 条

[1] Stereoselective single-step synthesis and X-ray crystallographic investigation of acetylated aryl 1,2-trans glycopyranosides and aryl 1,2-cis C2-hydroxy-glycopyranosides [J].

Aich, U ;

Loganathan, D .

CARBOHYDRATE RESEARCH, 2006, 341 (01) :19-28

[2] Zeolite-catalyzed Helferich-type glycosylation of long-chain alcohols.: Synthesis of acetylated alkyl 1,2-trans glycopyranosides and alkyl 1,2-cis C2-hydroxy-glycopyranosides [J].

Aich, Udayanath ;

Loganathan, Duraikkannu .

CARBOHYDRATE RESEARCH, 2007, 342 (05) :704-709

[3] Selective conversion of nitroalcohols into nitroolefins over zeolite under heterogeneous conditions [J].

Anbazhagan, M ;

Kumaran, G ;

Sasidharan, M .

JOURNAL OF CHEMICAL RESEARCH-S, 1997, (09) :336-337

[4]

[Anonymous], 2001, FINE CHEM HETEROGENE

[5] A facile and selective synthesis of beta-keto esters via zeolite catalysed transesterification [J].

Balaji, BS ;

Sasidharan, M ;

Kumar, R ;

Chanda, B .

CHEMICAL COMMUNICATIONS, 1996, (06) :707-708

[6] Zeolite catalyzed selective deprotection of di- and tri-O-isopropylidene sugar acetals [J].

Bhaskar, Pallooru Muni ;

Mathiselvam, Manoharan ;

Loganathan, Duraikkannu .

CARBOHYDRATE RESEARCH, 2008, 343 (10-11) :1801-1807

[7]

Bhaskar PM, 1999, SYNLETT, P129

[8] Per-O-acetylation of sugars catalysed by montmorillonite K-10 [J].

Bhaskar, PM ;

Loganathan, D .

TETRAHEDRON LETTERS, 1998, 39 (15) :2215-2218

[9] Acylation of toluene with acetic anhydride over beta zeolites:: Influence of reaction conditions and physicochemical properties of the catalyst [J].

Botella, P ;

Corma, A ;

López-Nieto, JM ;

Valencia, S ;

Jacquot, R .

JOURNAL OF CATALYSIS, 2000, 195 (01) :161-168

[10] Stereoselective synthesis of [13C]methyl 2-[15N]amino-2-deoxy-β-D-glucopyranoside derivatives [J].

Boulineau, FP ;

Wei, A .

CARBOHYDRATE RESEARCH, 2001, 334 (04) :271-279

← 1 2 3 4 5 6 7 8 9 10 →