Composition and processing effects on the electrochemical characteristics of biomedical titanium alloys

被引:104
作者
Cvijovic-Alagic, I. [1 ]
Cvijovic, Z. [2 ]
Bajat, J. [2 ]
Rakin, M. [2 ]
机构
[1] Univ Belgrade, Inst Nucl Sci Vinca, Belgrade 11001, Serbia
[2] Univ Belgrade, Fac Technol & Met, Belgrade 11120, Serbia
关键词
Titanium; Alloys; XRD; Passive films; Polarization; EIS; IN-VITRO CORROSION; TI-13NB-13ZR ALLOY; PHYSIOLOGICAL SOLUTION; IMPEDANCE SPECTROSCOPY; OXIDE-FILMS; ORTHOPEDIC TIALV; FATIGUE BEHAVIOR; RINGERS SOLUTION; IMPLANT ALLOYS; HANKS SOLUTION;
D O I
10.1016/j.corsci.2014.02.017
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
The electrochemical behaviour of the Ti-13Nb-13Zr and Ti-6Al-4V ELI alloys with martensitic microstructures was investigated by polarization and electrochemical impedance spectroscopy (EIS) in Ringer's solution. The impedance spectra were interpreted by a two time-constants equivalent circuit. Both investigated alloys showed high corrosion resistance, but the thin and uniform passive film on the Ti-6Al-4V ELI alloy surface was more protective. The inner barrier and outer porous layer were highly resistant and capacitive. However, thicker and more porous passive film on the Ti-13Nb-13Zr alloy surface may be beneficial for osteointegration. The suitable thermomechanical processing improved the corrosion resistance of Ti-13Nb-13Zr alloy. (c) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:245 / 254
页数:10
相关论文
共 58 条
[1]
Phase transformations during cooling in α+β titanium alloys [J].
Ahmed, T ;
Rack, HJ .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1998, 243 (1-2) :206-211
[2]
In situ impedance spectroscopy study of the electrochemical corrosion of Ti and Ti-6Al-4V in simulated body fluid at 25 °C and 37 °C [J].
Alves, V. A. ;
Reis, R. Q. ;
Santos, I. C. B. ;
Souza, D. G. ;
Goncalves, T. de F. ;
Pereira-da-Silva, M. A. ;
Rossi, A. ;
da Silva, L. A. .
CORROSION SCIENCE, 2009, 51 (10) :2473-2482
[3]
PREPARATION AND SURFACE SPECTROSCOPIC CHARACTERIZATION OF OXIDE-FILMS ON TI6A14V [J].
ASK, M ;
LAUSMAA, J ;
KASEMO, B .
APPLIED SURFACE SCIENCE, 1989, 35 (03) :283-301
[4]
The electrochemical behaviour of Ti-13Nb-13Zr alloy in various solutions [J].
Assis, S. L. ;
Wolynec, S. ;
Costa, I. .
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2008, 59 (09) :739-743
[5]
Electrochemical evaluation of Ti-13Nb-13Zr, Ti-6Al-4V and Ti-6Al-7Nb alloys for biomedical application by long-term immersion tests [J].
Assis, S. L. ;
Costa, I. .
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2007, 58 (05) :329-333
[6]
A comparative study of the in vitro corrosion behavior and cytotoxicity of a superferritic stainless steel, a Ti-13Nb-13Zr alloy, and an austenitic stainless steel in Hank's solution [J].
Assis, SL ;
Rogero, SO ;
Antunes, RA ;
Padilha, AF ;
Costa, I .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART B-APPLIED BIOMATERIALS, 2005, 73B (01) :109-116
[7]
Corrosion Behavior of Ti-6Al-4V with Different Thermomechanical Treatments and Microstructures [J].
Atapour, M. ;
Pilchak, A. ;
Frankel, G. S. ;
Williams, J. C. ;
Fathi, M. H. ;
Shamanian, M. .
CORROSION, 2010, 66 (06)
[8]
Fatigue behavior of arc melted Ti-13Nb-13Zr alloy [J].
Baptista, CARP ;
Schneider, SG ;
Taddei, EB ;
da Silva, HM .
INTERNATIONAL JOURNAL OF FATIGUE, 2004, 26 (09) :967-973
[9]
The effect of temperature on the nucleation of corrosion pits on titanium in Ringer's physiological solution [J].
Burstein, GT ;
Liu, C ;
Souto, RM .
BIOMATERIALS, 2005, 26 (03) :245-256
[10]
Choubey A., 2005, Trends Biomater. Artif. Organs, V18, P64