Exploration of the possibilities for production of Fischer Tropsch liquids and power via biomass gasification

被引:649
作者
Tijmensen, MJA
Faaij, APC
Hamelinck, CN
van Hardeveld, MRM
机构
[1] Univ Utrecht, Dept Sci Technol & Soc, NL-3584 CH Utrecht, Netherlands
[2] Shell Global Solut Int BV, NL-1030 BN Amsterdam, Netherlands
关键词
biomass; gasification; Fischer Tropsch synthesis; FT-liquids; polygeneration; diesel; combined cycle;
D O I
10.1016/S0961-9534(02)00037-5
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
This paper reviews the technical feasibility and economics of biomass integrated gasification-Fischer Tropsch (BIG-FT) processes in general, identifies most promising system configurations and identifies key R&D issues essential for the commercialisation of BIG-FT technology. The FT synthesis produces hydrocarbons of different length from a gas mixture of H-2 and CO. The large hydrocarbons can be hydrocracked to form mainly diesel of excellent quality. The fraction of short hydrocarbons is used in a combined cycle with the remainder of the syngas. Overall LHV energy efficiencies,(1) calculated with the flowsheet modelling tool Aspen(plus), are 33-40% for atmospheric gasification systems and 42-50% for pressurised gasification systems. Investment costs of such systems (367 MWth) are MUS$ 280-450,(2) depending on the system configuration. In the short term, production costs of FT-liquids will be about US$ 16/GJ. In the longer term, with large-scale production, higher CO conversion and higher C5+ selectivity in the FT process, production costs of FT-liquids could drop to US$ 9/GJ. These perspectives for this route and use of biomass-derived FT-fuels in the transport sector are promising. Research and development should be aimed at the development of large-scale (pressurised) biomass gasification-based systems and special attention must be given to the gas cleaning section. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:129 / 152
页数:24
相关论文
共 31 条
[1]  
Agee MA, 1998, STUD SURF SCI CATAL, V119, P931
[2]  
AMOCO BP, 1999, STAT REV WORLD ENERG
[3]  
CONSONNI S, 1994, COGEN TURBO POWER 19
[4]   Low temperature Fischer-Tropsch synthesis from a Sasol perspective [J].
Espinoza, RL ;
Steynberg, AP ;
Jager, B ;
Vosloo, AC .
APPLIED CATALYSIS A-GENERAL, 1999, 186 (1-2) :13-26
[5]  
Faaij A, 2001, GREENHOUSE GAS CONTROL TECHNOLOGIES, P1145
[6]   Gasification of biomass wastes and residues for electricity production [J].
Faaij, A ;
vanRee, R ;
Waldheim, L ;
Olsson, E ;
Oudhuis, A ;
vanWijk, A ;
DaeyOuwens, C ;
Turkenburg, W .
BIOMASS & BIOENERGY, 1997, 12 (06) :387-407
[7]  
FAAIJ A, 1998, LONG TERM PERSPECTIV
[8]  
FAAIJ A, 2001, P 1 WORLD C BIOM EN, V1, P687
[9]   Fischer-Tropsch technology - from active site to commercial process [J].
Geerlings, JJC ;
Wilson, JH ;
Kramer, GJ ;
Kuipers, HPCE ;
Hoek, A ;
Huisman, HM .
APPLIED CATALYSIS A-GENERAL, 1999, 186 (1-2) :27-40
[10]  
GOLDEMBERG, 2000, WORLD ENERGY ASSESSM