From eilatin to isoeilatin:: A skeletal rearrangement strongly influences π-stacking of Ru(II) complex

被引：26

作者：

Bergman, SD ^{[1
]}

Reshef, D ^{[1
]}

Frish, L ^{[1
]}

Cohen, Y ^{[1
]}

Goldberg, I ^{[1
]}

Kol, M ^{[1
]}

机构：

[1] Tel Aviv Univ, Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 13期

关键词：

D O I：

10.1021/ic049806g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Cl-symmetrical complex [Ru(bpy)(2)(ieil)][PF6](2) exhibits unique electrochemical and photophysical properties, and forms discrete dimers in solution and in the solid state held by weak stacking interactions via its isoeilatin ligand, preferentially from one of its faces and in a specific orientation.

引用

页码：3792 / 3794

页数：3

共 22 条

[1] Luminescent and redox-active polynuclear transition metal complexes [J].

Balzani, V ;

Juris, A ;

Venturi, M ;

Campagna, S ;

Serroni, S .

CHEMICAL REVIEWS, 1996, 96 (02) :759-833

[2] Mononuclear and dinuclear complexes of dibenzoeilatin: Synthesis, structure, and electrochemical and photophysical properties [J].

Bergman, SD ;

Goldberg, I ;

Barbieri, A ;

Barigelletti, F ;

Kol, M .

INORGANIC CHEMISTRY, 2004, 43 (07) :2355-2367

[3] Dibenzoeilatin:: a novel ligand exhibiting remarkable complementary π-π stacking interactions [J].

Bergman, SD ;

Reshef, D ;

Groysman, S ;

Goldberg, I ;

Kol, M .

CHEMICAL COMMUNICATIONS, 2002, (20) :2374-2375

[4] SELF-DIFFUSION OF CHARGED POLYCYCLIC SYSTEMS AND THEIR PARENT COMPOUNDS - A PGSE NMR-STUDY [J].

COHEN, Y ;

AYALON, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07) :816-818

[5] Compensation of steric demand by cation-π interactions, cobaltocenium cations as guests in tetraurea calix[4] arene dimers [J].

Frish, L ;

Vysotsky, MO ;

Böhmer, V ;

Cohen, Y .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2003, 1 (11) :2011-2014

[6] THE BIOMIMETIC SYNTHESIS OF MARINE ALKALOID RELATED PYRIDO[2,3,4-KL]ACRIDINES AND PYRROLO[2,3,4-KL]ACRIDINES [J].

GELLERMAN, G ;

RUDI, A ;

KASHMAN, Y .

TETRAHEDRON, 1994, 50 (45) :12959-12972

[7] A PFG NMR EXPERIMENT FOR ACCURATE DIFFUSION AND FLOW STUDIES IN THE PRESENCE OF EDDY CURRENTS [J].

GIBBS, SJ ;

JOHNSON, CS .

JOURNAL OF MAGNETIC RESONANCE, 1991, 93 (02) :395-402

[8] Eilatin as a bridging ligand in ruthenium(II) complexes: Synthesis, crystal structures, absorption spectra, and electrochemical properties [J].

Gut, D ;

Goldberg, I ;

Kol, M .

INORGANIC CHEMISTRY, 2003, 42 (11) :3483-3491

[9] Pairing of propellers:: Dimerization of octahedral ruthenium(II) and osmium(II) complexes of eilatin via π-π stacking featuring heterochiral recognition [J].

Gut, D ;

Rudi, A ;

Kopilov, J ;

Goldberg, I ;

Kol, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (19) :5449-5456

[10] RU(II) POLYPYRIDINE COMPLEXES - PHOTOPHYSICS, PHOTOCHEMISTRY, ELECTROCHEMISTRY, AND CHEMI-LUMINESCENCE [J].

JURIS, A ;

BALZANI, V ;

BARIGELLETTI, F ;

CAMPAGNA, S ;

BELSER, P ;

VONZELEWSKY, A .

COORDINATION CHEMISTRY REVIEWS, 1988, 84 :85-277

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