First enantioselective allylic etherification with phenols catalyzed by chiral ruthenium bisoxazoline complexes

被引：72

作者：

Mbaye, MD ^{[1
]}

Renaud, JL ^{[1
]}

Demerseman, B ^{[1
]}

Bruneau, C ^{[1
]}

机构：

[1] Univ Rennes 1, Inst Chim, UMR 6509, F-35042 Rennes, France

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 16期

关键词：

D O I：

10.1039/b406039c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Regio- and enantioselective substitution of cinnamyl chloride by phenols has been achieved with up to 82% enantiomeric excess, using a ruthenium catalyst prepared from [Cp*(CH3CN)(3)Ru][PF6] and a chiral bisoxazoline ligand.

引用

页码：1870 / 1871

页数：2

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