Asymmetric palladium(0)-mediated synthesis of 2-vinylchroman

被引：43

作者：

Labrosse, JR ^{[1
]}

Poncet, C ^{[1
]}

Lhoste, P ^{[1
]}

Sinou, D ^{[1
]}

机构：

[1] Univ Lyon 1, CPE Lyon, CNRS, Lab Synthese Asymetr, F-69622 Villeurbanne, France

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 06期

关键词：

D O I：

10.1016/S0957-4166(99)00077-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Optically active 2-vinylchroman was synthesized from the corresponding hydroxy allylic carbonate by palladium-catalyzed cyclization in the presence of various chiral ligands. Enantioselectivity of up to 53% was obtained using NMDPP as the chiral phosphine. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1069 / 1078

页数：10

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