Characterizations of crystalline structure and electrical properties of pyrolyzed polyfurfuryl alcohol

被引:34
作者
Wang, ZX [1 ]
Lu, ZH [1 ]
Huang, YZ [1 ]
Xue, RJ [1 ]
Huang, XJ [1 ]
Chen, LQ [1 ]
机构
[1] CHINESE ACAD SCI,INST PHYS,NATL LAB SUPERCOND,BEIJING 100080,PEOPLES R CHINA
关键词
D O I
10.1063/1.366434
中图分类号
O59 [应用物理学];
学科分类号
摘要
Polyfurfuryl alcohol (PFA) is pyrolyzed at 600 degrees C for different lengths of heat-treatment (HT) time (0-50 h) and at different pyrolytic temperatures (600-850 degrees C) for 4 h. Analysis by Raman spectroscopy shows that the crystallite size of PFA pyrolyzed at 600 degrees C decreases with increasing HT time. This suggestion is supported by the electrical conductivity measurements on PFA samples pyrolyzed at different HT temperatures and at 600 degrees C for different HT times, A trend of transition from semiconductive to metallic properties is suggested for the samples prepared above 850 degrees C. (C) 1997 American Institute of Physics.
引用
收藏
页码:5705 / 5710
页数:6
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