Highly selective 1,6-addition of aryl boronic acids to α,β,γ,δ-unsaturated carbonyl compounds catalyzed by an iridium complex

被引：61

作者：

Nishimura, Takahiro ^{[1
]}

Yasuhara, Yuichi ^{[1
]}

Hayashi, Tanno ^{[1
]}

机构：

[1] Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 31期

关键词：

1,6-addition; arylation; boronic acids; iridium; regioselectivity;

D O I：

10.1002/anie.200601719

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

(Chemical Equation Presented) Perfect control: The catalytic 1,6-addition of aryl boronic acids to electron-deficient dienes was realized by use of an iridium catalyst (see scheme). High yields of the corresponding δ-arylated carbonyl compounds were obtained with perfect 1,6-selectivity. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5164 / 5166

页数：3

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