Self assembly of a novel water soluble iron(II) macrocyclic phosphine complex from tetrakis(hydroxymethyl)phosphonium sulfate and iron(II) ammonium sulfate:: single crystal X-ray structure of the complex [Fe(H2O)2{RP(CH2N(CH2PR2)CH2)2PR}]SO4•4H2O (R = CH2OH)

被引：26

作者：

Jeffery, JC

Odell, B

Stevens, N

Talbot, RE

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] Univ Oxford, Dyson Perrins Lab, Oxford OX1 3QY, England

[3] Albright & Wilson UK Ltd, Oldbury B69 4LN, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 01期

关键词：

D O I：

10.1039/a908309j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The water soluble Fe(ii) macrocyclic phosphine complex [Fe(H2O)(2){RP(CH2N(CH2PR2)CH2)(2)PR}]SO4. 4H(2)O (R = CH2OH) has been characterised by single crystal X-ray diffraction and is formed by a remarkable self-assembly reaction between iron(II) ammonium sulfate and tetrakis(hydroxymethyl)phosphonium sulfate (THPS).

引用

页码：101 / 102

页数：2

共 7 条

[1] WATER-SOLUBLE ORGANOMETALLIC COMPOUNDS .4. CATALYTIC-HYDROGENATION OF ALDEHYDES IN AN AQUEOUS 2-PHASE SOLVENT SYSTEM USING A 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE COMPLEX OF RUTHENIUM [J].