Formation and X-ray structure of a novel water-soluble tertiary-secondary phosphine complex of ruthenium(II):: [Ru{P(CH2OH)3}2{P(CH2OH)2H}2Cl2]

被引：31

作者：

Higham, L ^{[1
]}

Powell, AK ^{[1
]}

Whittlesey, MK ^{[1
]}

Wocadlo, S ^{[1
]}

Wood, PT ^{[1
]}

机构：

[1] Univ E Anglia, Sch Chem Sci, Norwich NR4 7TJ, Norfolk, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 10期

关键词：

D O I：

10.1039/a801546e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel secondary-tertiary hydroxymethylphosphine complex, all-trans [Ru{P(CH2OH)(3)}(2){P(CH2OH)(2)H}(2)Cl-2], is formed by the room temperature reaction of excess tris(hydroxymethyl)phosphine, P(CH2OH)(3), with either RuCl3 . H2O or [Ru(PPh3)(3)Cl-2]; the X-ray crystal structure of the complex shows extensive intra-and inter-molecular hydrogen bonding consistent with the high water solubility of the complex.

引用

页码：1107 / 1108

页数：2

共 20 条

[1] Synthesis and catalytic chemistry of two new water-soluble chelating phosphines - Comparison of ionic and nonionic functionalities [J].

Baxley, GT ;

Weakley, TJR ;

Miller, WK ;

Lyon, DK ;

Tyler, DR .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 116 (1-2) :191-198

[2] Synthesis and characterization of water-soluble 1,2-bis(bis(hydroxyalkyl)phosphino)ethane ligands and their nickel(II), ruthenium(III), and rhodium(I) complexes [J].

Baxley, GT ;

Miller, WK ;

Lyon, DK ;

Miller, BE ;

Nieckarz, GF ;

Weakley, TJR ;

Tyler, DR .

INORGANIC CHEMISTRY, 1996, 35 (23) :6688-6693

[3] In vitro and in vivo characterization of a Tc-99m complex with tris(hydroxymethyl)phosphine (THP) [J].

Berning, DE ;

Katti, KV ;

Singh, PR ;

Higgenbotham, C ;

Reddy, VS ;

Volkert, WA .

NUCLEAR MEDICINE AND BIOLOGY, 1996, 23 (05) :617-622

[4] Chemistry in environmentally benign media .8. Hydroxymethyl functionalized phosphanes as building blocks to new water-soluble gold(I) complexes - Synthesis, characterization, and X-ray crystal structures of novel tetrahedral [Au{P(CH2OH)(3)}(4)](+) and trigonal planar [Au(Ph2PCH2OH)(3)](+) gold(I) complexes [J].

Berning, DE ;

Katti, KV ;

Barnes, CL ;

Volkert, WA .

CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (07) :907-911

[5] Multifaceted reactions of P(CH2OH)3 with rhenium(V) precursors.: Synthesis, characterization, and X-ray structural studies of trans,trans,trans-[ReO2{P(CH2OH)3}2(py)2]Cl, trans,cis,cis-[ReO2{P(CH2OH)3}2(py)2]Cl, and novel alkoxide [Re(O)(μ-O)-(P{CH2OH}3)(μ-η2-P{CH2OH}2CH2O)]4 [J].

Berning, DE ;

Katti, KV ;

Barbour, LJ ;

Volkert, WA .

INORGANIC CHEMISTRY, 1998, 37 (02) :334-339

[6] RHODIUM(I), RHODIUM(III), PALLADIUM(II), AND PLATINUM(II) COMPLEXES CONTAINING LIGANDS OF TYPE PRNQ3-N(N=0,1, OR 2 R = ME, ET, BUT, OR PH Q = CH2OCOME OR CH2OH) [J].

CHATT, J ;

LEIGH, GJ ;

SLADE, RM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (19) :2021-2028

[7] WATER-SOLUBLE ORGANOMETALLIC COMPOUNDS .2. CATALYTIC-HYDROGENATION OF ALDEHYDES AND OLEFINS BY NEW WATER-SOLUBLE 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE COMPLEXES OF RUTHENIUM AND RHODIUM [J].

DARENSBOURG, DJ ;

JOO, F ;

KANNISTO, M ;

KATHO, A ;

REIBENSPIES, JH .

ORGANOMETALLICS, 1992, 11 (06) :1990-1993

[8] WATER-SOLUBLE ORGANOMETALLIC COMPOUNDS .4. CATALYTIC-HYDROGENATION OF ALDEHYDES IN AN AQUEOUS 2-PHASE SOLVENT SYSTEM USING A 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE COMPLEX OF RUTHENIUM [J].

DARENSBOURG, DJ ;

JOO, F ;

KANNISTO, M ;

KATHO, A ;

REIBENSPIES, JH ;

DAIGLE, DJ .

INORGANIC CHEMISTRY, 1994, 33 (02) :200-208

[9] WATER-SOLUBLE TRIS(HYDROXYMETHYL)PHOSPHINE COMPLEXES WITH NICKEL, PALLADIUM, AND PLATINUM - CRYSTAL-STRUCTURE OF [PD(P(CH2OH)3)4].CH3OH [J].

ELLIS, JW ;

HARRISON, KN ;

HOYE, PAT ;

ORPEN, AG ;

PRINGLE, PG ;

SMITH, MB .

INORGANIC CHEMISTRY, 1992, 31 (14) :3026-3033

[10]

FRANK AW, 1982, TEXT RES J, P678

← 1 2 →