New heteroleptic iridium complexes having one biphenyl-2,2′-diyl and two bipyridyl based ligands
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作者:
Lee, Kyu Reon
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Sogang Univ, Dept Chem, Seoul 121742, South KoreaSogang Univ, Dept Chem, Seoul 121742, South Korea
Lee, Kyu Reon
[1
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Eum, Min-Sik
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Sogang Univ, Dept Chem, Seoul 121742, South KoreaSogang Univ, Dept Chem, Seoul 121742, South Korea
Eum, Min-Sik
[1
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Chin, Chong Shik
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Sogang Univ, Dept Chem, Seoul 121742, South KoreaSogang Univ, Dept Chem, Seoul 121742, South Korea
Chin, Chong Shik
[1
]
Lee, Seung Chan
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Hongik Univ, Dept Sci, Seoul 121791, South Korea
Hongik Univ, Dept Informat Display Engn, Seoul 121791, South KoreaSogang Univ, Dept Chem, Seoul 121742, South Korea
Lee, Seung Chan
[2
,3
]
Kim, In June
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Hongik Univ, Dept Sci, Seoul 121791, South Korea
Hongik Univ, Dept Informat Display Engn, Seoul 121791, South KoreaSogang Univ, Dept Chem, Seoul 121742, South Korea
Kim, In June
[2
,3
]
Kim, Young Sik
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Hongik Univ, Dept Sci, Seoul 121791, South Korea
Hongik Univ, Dept Informat Display Engn, Seoul 121791, South KoreaSogang Univ, Dept Chem, Seoul 121742, South Korea
Kim, Young Sik
[2
,3
]
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Kim, Youngmee
[4
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Kim, Sung-Jin
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Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South KoreaSogang Univ, Dept Chem, Seoul 121742, South Korea
Kim, Sung-Jin
[4
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Hur, Nam Hwi
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Sogang Univ, Dept Chem, Seoul 121742, South KoreaSogang Univ, Dept Chem, Seoul 121742, South Korea
Hur, Nam Hwi
[1
]
机构:
[1] Sogang Univ, Dept Chem, Seoul 121742, South Korea
[2] Hongik Univ, Dept Sci, Seoul 121791, South Korea
[3] Hongik Univ, Dept Informat Display Engn, Seoul 121791, South Korea
[4] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea
The structural and spectroscopic properties of new heteroleptic iridium complexes having a biphenyl and two bipyridyl based ligands are reported; DFT calculations reveal that the HOMO is composed of the biphenyl and iridium d orbitals while the LUMO is localized mainly on the two bipyridyl based ligands.