New heteroleptic iridium complexes having one biphenyl-2,2′-diyl and two bipyridyl based ligands

被引：19

作者：

Lee, Kyu Reon ^{[1
]}

Eum, Min-Sik ^{[1
]}

Chin, Chong Shik ^{[1
]}

Lee, Seung Chan ^{[2
,3
]}

Kim, In June ^{[2
,3
]}

Kim, Young Sik ^{[2
,3
]}

Kim, Youngmee ^{[4
]}

Kim, Sung-Jin ^{[4
]}

Hur, Nam Hwi ^{[1
]}

机构：

[1] Sogang Univ, Dept Chem, Seoul 121742, South Korea

[2] Hongik Univ, Dept Sci, Seoul 121791, South Korea

[3] Hongik Univ, Dept Informat Display Engn, Seoul 121791, South Korea

[4] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea

来源：

DALTON TRANSACTIONS | 2009年 / 19期

关键词：

EXCITED-STATE PROPERTIES; PHOSPHORESCENT EMISSION; BLUE; MECHANISM;

D O I：

10.1039/b904016c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structural and spectroscopic properties of new heteroleptic iridium complexes having a biphenyl and two bipyridyl based ligands are reported; DFT calculations reveal that the HOMO is composed of the biphenyl and iridium d orbitals while the LUMO is localized mainly on the two bipyridyl based ligands.

引用

收藏

页码：3650 / 3652

页数：3

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