A two-step synthesis of new macrobicyclic aza-ligands starting from ''trans''dioxocyclam as diprotected macrocycle

被引：37

作者：

Denat, F ^{[1
]}

Lacour, S ^{[1
]}

Brandes, S ^{[1
]}

Guilard, R ^{[1
]}

机构：

[1] UNIV BOURGOGNE,LAB INGN MOL SEPARAT & APPLICAT GRAZ,LIMSAG,UMR 5633,F-21000 DIJON,FRANCE

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 25期

关键词：

D O I：

10.1016/S0040-4039(97)00944-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A rapid and convenient synthesis of two small aza-cryptands containing a 1,4,8,11-tetraazacyclotetradecane backbone is reported. This strategy can be applied to the preparation of many other aza-cages by varying the nature of the cross linker. Moreover, the two remaining secondary amine sites may allow the functionalization of these ligands or their grafting on a polymer. (C) 1997 Published by Elsevier Science Ltd.

引用

页码：4417 / 4420

页数：4

共 26 条

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